An expedient synthesis of D-callipeltose

Ainoliisa J. Pihko; K.C. Nicolaou; Ari M.P. Koskinen

doi:10.1016/S0957-4166(01)00146-X

An expedient synthesis of D-callipeltose

Ainoliisa J. Pihko
, K.C. Nicolaou
, Ari M.P. Koskinen

Tutkimustuotos: Lehtiartikkeli › Article › Scientific › vertaisarvioitu

32 Viittaukset (Web of Science)

301 Lataukset (Pure)

Abstrakti

Methyl D-callipeltose 12 and D-callipeltose 4 were synthesized from D-glucal 5 in 10 and 11 steps, respectively. The synthesis features an azide displacement reaction of an -nosyloxy ketone 7 and a highly diastereoselective C-methylation of
alpha-azido ketone 8.

Alkuperäiskieli	Englanti
Sivut	937-942
Julkaisu	TETRAHEDRON-ASYMMETRY
Vuosikerta	12
DOI - pysyväislinkit	https://doi.org/10.1016/S0957-4166(01)00146-X
Tila	Julkaistu - 2001
OKM-julkaisutyyppi	A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä

Tutkimusalat

azides
D-callipeltose
D-glucal
diastereoselective synthesis

Pääsy asiakirjaan

10.1016/S0957-4166(01)00146-X

ms083Accepted author manuscript, 96,8 KB

Siteeraa tätä

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title = "An expedient synthesis of D-callipeltose",

abstract = "Methyl D-callipeltose 12 and D-callipeltose 4 were synthesized from D-glucal 5 in 10 and 11 steps, respectively. The synthesis features an azide displacement reaction of an -nosyloxy ketone 7 and a highly diastereoselective C-methylation of alpha-azido ketone 8.",

keywords = "azides, D-callipeltose, D-glucal, diastereoselective synthesis, azides, D-callipeltose, D-glucal, diastereoselective synthesis, azides, D-callipeltose, D-glucal, diastereoselective synthesis",

author = "Pihko, \{Ainoliisa J.\} and K.C. Nicolaou and Koskinen, \{Ari M.P.\}",

year = "2001",

doi = "10.1016/S0957-4166(01)00146-X",

language = "English",

volume = "12",

pages = "937--942",

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T1 - An expedient synthesis of D-callipeltose

AU - Pihko, Ainoliisa J.

AU - Nicolaou, K.C.

AU - Koskinen, Ari M.P.

PY - 2001

Y1 - 2001

N2 - Methyl D-callipeltose 12 and D-callipeltose 4 were synthesized from D-glucal 5 in 10 and 11 steps, respectively. The synthesis features an azide displacement reaction of an -nosyloxy ketone 7 and a highly diastereoselective C-methylation of alpha-azido ketone 8.

AB - Methyl D-callipeltose 12 and D-callipeltose 4 were synthesized from D-glucal 5 in 10 and 11 steps, respectively. The synthesis features an azide displacement reaction of an -nosyloxy ketone 7 and a highly diastereoselective C-methylation of alpha-azido ketone 8.

KW - azides

KW - D-callipeltose

KW - D-glucal

KW - diastereoselective synthesis

KW - azides

KW - D-callipeltose

KW - D-glucal

KW - diastereoselective synthesis

KW - azides

KW - D-callipeltose

KW - D-glucal

KW - diastereoselective synthesis

U2 - 10.1016/S0957-4166(01)00146-X

DO - 10.1016/S0957-4166(01)00146-X

M3 - Article

SN - 0957-4166

VL - 12

SP - 937

EP - 942

JO - TETRAHEDRON-ASYMMETRY

JF - TETRAHEDRON-ASYMMETRY

ER -

An expedient synthesis of D-callipeltose

Abstrakti

Tutkimusalat

Pääsy asiakirjaan

Sormenjälki

Siteeraa tätä