A sustainable two-layer lignin-anodized composite coating for the corrosion protection of high-strength low-alloy steel

Arman Dastpak; Pyry Mikko Hannula; Mari Lundström; Benjamin P. Wilson

doi:10.1016/j.porgcoat.2020.105866

A sustainable two-layer lignin-anodized composite coating for the corrosion protection of high-strength low-alloy steel

Arman Dastpak
, Pyry Mikko Hannula
, Mari Lundström
, Benjamin P. Wilson^*

^*Tämän työn vastaava kirjoittaja

Tutkimustuotos: Lehtiartikkeli › Article › Scientific › vertaisarvioitu

25 Sitaatiot (Scopus)

148 Lataukset (Pure)

Abstrakti

In this study, plasticized kraft lignin was used to prepare anti-corrosive coatings on steel, which was galvanostatically anodized (80 °C, 25 wt.% NaOH) by utilizing three different current density values (24, 50 and 120 mA/cm²). It was shown that the anodization affects not only the properties of anodic coatings but also their interaction with lignin coatings. A combination of pull-off adhesion measurements with linear sweep voltammetry (LSV) demonstrated an enhanced adhesion strength of plasticized lignin coatings (4.32 MPa on anodized surface vs. 2.38 MPa on bare steel) and decreased corrosion current density from 15 μA/cm² (bare steel) up to ca. 0.5 μA/cm² for anodized and lignin coated steel.

Alkuperäiskieli	Englanti
Artikkeli	105866
Sivumäärä	9
Julkaisu	Progress in Organic Coatings
Vuosikerta	148
DOI - pysyväislinkit	https://doi.org/10.1016/j.porgcoat.2020.105866
Tila	Julkaistu - marrask. 2020
OKM-julkaisutyyppi	A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä

Rahoitus

This research was funded by Technology Industries of Finland/Jane and Aatos Erkko Foundations, Academy of Finland “ Future Makers: Biorefinery Side Stream Materials for Advanced Biopolymer Materials (BioPolyMet) ” and Academy of Finland (NoWASTE, No. 297962 ). Furthermore, this work utilized facilities provided by the RawMatTERS Finland Infrastructure (RAMI), supported by the Academy of Finland, as well as OtaNano Infrastructure at Aalto University. We also are grateful for the support by the Finn CERES Materials Bioeconomy Ecosystem. Additionally, special thanks to Esa Virolainen (SSAB Europe Oy) for providing steel sheets, and Michal Trebala for conducting nanomechanical analysis of the coatings of this study.

Pääsy asiakirjaan

10.1016/j.porgcoat.2020.105866Lisenssi: CC BY-NC-ND

1-s2.0-S0300944020306172-mainFinal published version, 3,03 MBLisenssi: CC BY-NC-ND

Muut tiedostot ja linkit

Link to publication in Scopus

FinnCERES: Competence Center for the Materials Bioeconomy: A Flagship for our Sustainable Future
Mäkelä, K. (Vastuullinen johtaja)
01/05/2018 → 31/12/2022
Projekti: Academy of Finland: Other research funding
NoWASTE: Uudenlainen arvometallien talteenotto sivuvirroista
Lundström, M. (Vastuullinen johtaja), Hannula, P.-M. (Projektin jäsen), Yliniemi, K. (Projektin jäsen), Revitzer, H. (Projektin jäsen), Junnila, T. (Projektin jäsen), Kinnunen, S. (Projektin jäsen), Barranco Asensio, V. (Projektin jäsen), Karppinen, A. (Projektin jäsen), Wang, Z. (Projektin jäsen), Wilson, B. (Projektin jäsen) & Halli, P. (Projektin jäsen)
01/09/2016 → 31/12/2020
Projekti: Academy of Finland: Other research funding

OtaNano Nanomikroskopiakeskus
Seitsonen, J. (Manager) & Rissanen, A. (Other)
OtaNano
Laitteistot/tilat: Facility
Raaka-aineiden tutkimusinfrastruktuuri
Karppinen, M. (Manager)
Kemian tekniikan korkeakoulu
Laitteistot/tilat: Facility

Biopolymeric Anticorrosion Coatings from Cellulose Nanofibrils and Colloidal Lignin Particles
Dastpak, A., Ansell, P., Searle, J. R., Lundström, M. & Wilson, B. P., 1 syysk. 2021, julkaisussa: ACS Applied Materials and Interfaces. 13, 34, s. 41034-41045 12 Sivumäärä
Tutkimustuotos: Lehtiartikkeli › Article › Scientific › vertaisarvioitu

Open access
Tiedosto
28 Sitaatiot (Scopus)

105 Lataukset (Pure)

Siteeraa tätä

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title = "A sustainable two-layer lignin-anodized composite coating for the corrosion protection of high-strength low-alloy steel",

abstract = "In this study, plasticized kraft lignin was used to prepare anti-corrosive coatings on steel, which was galvanostatically anodized (80 °C, 25 wt.\% NaOH) by utilizing three different current density values (24, 50 and 120 mA/cm2). It was shown that the anodization affects not only the properties of anodic coatings but also their interaction with lignin coatings. A combination of pull-off adhesion measurements with linear sweep voltammetry (LSV) demonstrated an enhanced adhesion strength of plasticized lignin coatings (4.32 MPa on anodized surface vs. 2.38 MPa on bare steel) and decreased corrosion current density from 15 μA/cm2 (bare steel) up to ca. 0.5 μA/cm2 for anodized and lignin coated steel.",

keywords = "Biopolymer, Corrosion protection, Organic coating, Oxide coating, Steel",

author = "Arman Dastpak and Hannula, \{Pyry Mikko\} and Mari Lundstr{\"o}m and Wilson, \{Benjamin P.\}",

year = "2020",

month = nov,

doi = "10.1016/j.porgcoat.2020.105866",

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volume = "148",

journal = "Progress in Organic Coatings",

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T1 - A sustainable two-layer lignin-anodized composite coating for the corrosion protection of high-strength low-alloy steel

AU - Dastpak, Arman

AU - Hannula, Pyry Mikko

AU - Lundström, Mari

AU - Wilson, Benjamin P.

PY - 2020/11

Y1 - 2020/11

N2 - In this study, plasticized kraft lignin was used to prepare anti-corrosive coatings on steel, which was galvanostatically anodized (80 °C, 25 wt.% NaOH) by utilizing three different current density values (24, 50 and 120 mA/cm2). It was shown that the anodization affects not only the properties of anodic coatings but also their interaction with lignin coatings. A combination of pull-off adhesion measurements with linear sweep voltammetry (LSV) demonstrated an enhanced adhesion strength of plasticized lignin coatings (4.32 MPa on anodized surface vs. 2.38 MPa on bare steel) and decreased corrosion current density from 15 μA/cm2 (bare steel) up to ca. 0.5 μA/cm2 for anodized and lignin coated steel.

AB - In this study, plasticized kraft lignin was used to prepare anti-corrosive coatings on steel, which was galvanostatically anodized (80 °C, 25 wt.% NaOH) by utilizing three different current density values (24, 50 and 120 mA/cm2). It was shown that the anodization affects not only the properties of anodic coatings but also their interaction with lignin coatings. A combination of pull-off adhesion measurements with linear sweep voltammetry (LSV) demonstrated an enhanced adhesion strength of plasticized lignin coatings (4.32 MPa on anodized surface vs. 2.38 MPa on bare steel) and decreased corrosion current density from 15 μA/cm2 (bare steel) up to ca. 0.5 μA/cm2 for anodized and lignin coated steel.

KW - Biopolymer

KW - Corrosion protection

KW - Organic coating

KW - Oxide coating

KW - Steel

UR - https://www.scopus.com/pages/publications/85088052115

U2 - 10.1016/j.porgcoat.2020.105866

DO - 10.1016/j.porgcoat.2020.105866

M3 - Article

AN - SCOPUS:85088052115

SN - 0300-9440

VL - 148

JO - Progress in Organic Coatings

JF - Progress in Organic Coatings

M1 - 105866

ER -

A sustainable two-layer lignin-anodized composite coating for the corrosion protection of high-strength low-alloy steel

Abstrakti

Rahoitus

Pääsy asiakirjaan

Muut tiedostot ja linkit

Sormenjälki

Projektit

FinnCERES: Competence Center for the Materials Bioeconomy: A Flagship for our Sustainable Future

NoWASTE: Uudenlainen arvometallien talteenotto sivuvirroista

Laitteet

OtaNano Nanomikroskopiakeskus

Raaka-aineiden tutkimusinfrastruktuuri

Tutkimustuotos

Biopolymeric Anticorrosion Coatings from Cellulose Nanofibrils and Colloidal Lignin Particles

Siteeraa tätä