A METHOD OF ALIGNING POLYMER CHAINS

MATTI KNAAPILA,; E HORSBURGH, LOCKHART,; P MONKMAN, ANDREW,; OLLI IKKALA,

A METHOD OF ALIGNING POLYMER CHAINS

MATTI KNAAPILA, (Keksijä), E HORSBURGH, LOCKHART, (Keksijä), P MONKMAN, ANDREW, (Keksijä), OLLI IKKALA, (Keksijä)

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Abstrakti

A hierarchical self-assembly in comb-shaped supramolecules of conjugated rod-like polymers and a novel concept to obtain the aligned solid state via cleaving side groups from the supramolecules are described. The supramolecules may consist of poly(2,5-pyridinediyl), acid dopants, and hydrogen bonded side chains. Films thereof are fluids even without an additional solvent and show thermotropic liquid crystallinity. They reveal exceptional degree of self-assembled order and the fluid state allows facile overall alignment yielding anisotropic opto-electronic properties, such as high dichroism and polarized emission. After alignment, cleavage of the side chains results in stable solid films with high optical anisotropy and enhanced photonic efficiency, such as improved photoluminescence quantum yield.

Alkuperäiskieli	Englanti
Patenttinumero	WO03082948
IPC	C09K 11/ 06 A I
Prioriteetti päiväys	28/03/2002
Tila	Julkaistu - 9 lokak. 2003
OKM-julkaisutyyppi	H1 Myönnetty patentti

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title = "A METHOD OF ALIGNING POLYMER CHAINS",

abstract = "A hierarchical self-assembly in comb-shaped supramolecules of conjugated rod-like polymers and a novel concept to obtain the aligned solid state via cleaving side groups from the supramolecules are described. The supramolecules may consist of poly(2,5-pyridinediyl), acid dopants, and hydrogen bonded side chains. Films thereof are fluids even without an additional solvent and show thermotropic liquid crystallinity. They reveal exceptional degree of self-assembled order and the fluid state allows facile overall alignment yielding anisotropic opto-electronic properties, such as high dichroism and polarized emission. After alignment, cleavage of the side chains results in stable solid films with high optical anisotropy and enhanced photonic efficiency, such as improved photoluminescence quantum yield.",

author = "MATTI KNAAPILA, and {HORSBURGH, LOCKHART,}, E and {MONKMAN, ANDREW,}, P and OLLI IKKALA,",

year = "2003",

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language = "English",

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note = "WO03082948; C09K 11/ 06 A I",

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AU - HORSBURGH, LOCKHART,, E

AU - MONKMAN, ANDREW,, P

AU - IKKALA,, OLLI

PY - 2003/10/9

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N2 - A hierarchical self-assembly in comb-shaped supramolecules of conjugated rod-like polymers and a novel concept to obtain the aligned solid state via cleaving side groups from the supramolecules are described. The supramolecules may consist of poly(2,5-pyridinediyl), acid dopants, and hydrogen bonded side chains. Films thereof are fluids even without an additional solvent and show thermotropic liquid crystallinity. They reveal exceptional degree of self-assembled order and the fluid state allows facile overall alignment yielding anisotropic opto-electronic properties, such as high dichroism and polarized emission. After alignment, cleavage of the side chains results in stable solid films with high optical anisotropy and enhanced photonic efficiency, such as improved photoluminescence quantum yield.

AB - A hierarchical self-assembly in comb-shaped supramolecules of conjugated rod-like polymers and a novel concept to obtain the aligned solid state via cleaving side groups from the supramolecules are described. The supramolecules may consist of poly(2,5-pyridinediyl), acid dopants, and hydrogen bonded side chains. Films thereof are fluids even without an additional solvent and show thermotropic liquid crystallinity. They reveal exceptional degree of self-assembled order and the fluid state allows facile overall alignment yielding anisotropic opto-electronic properties, such as high dichroism and polarized emission. After alignment, cleavage of the side chains results in stable solid films with high optical anisotropy and enhanced photonic efficiency, such as improved photoluminescence quantum yield.

M3 - Patent

M1 - WO03082948

ER -

A METHOD OF ALIGNING POLYMER CHAINS

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