2-Thioanyldichlorophosphine, new starting material for the preparation of multidentate phosphine ligands: syntheses and characterisation of derivatives of 2-anisyl- and 2-thioanisyldichlorophosphines

R.H Laitinen; V. Heikkinen; M. Haukka; A.M.P. Koskinen; J. Pursiainen

doi:10.1016/S0022-328X(99)00711-1

2-Thioanyldichlorophosphine, new starting material for the preparation of multidentate phosphine ligands: syntheses and characterisation of derivatives of 2-anisyl- and 2-thioanisyldichlorophosphines

R.H Laitinen, V. Heikkinen, M. Haukka, A.M.P. Koskinen, J. Pursiainen

Tutkimustuotos: Lehtiartikkeli › Article › Scientific › vertaisarvioitu

106 Lataukset (Pure)

Abstrakti

A new aryldichlorophosphine, 2-thioanisyldichlorophosphine, and its anisyl analogue, 2-anisyldichlorophosphine, were prepared by using an organozinc halide reagent of 2-thioanisole or 2-anisole with ethereal solution of PCl3 in refluxing conditions. From these aryldichlorophosphines, eight new multidentate phosphine ligands containing 2-thioanisyl, 4-thioanisyl, 2-anisyl, 1-naphthyl and 9-anthracenyl groups were synthesized and characterized. Characterization was based mainly on NMR spectroscopy and X-ray crystallography. The crystal structures of six ligands are reported. The electronic effects on basicity of ligands
are discussed.

Alkuperäiskieli	Englanti
Sivut	235-242
Julkaisu	Journal of Organometallic Chemistry
Numero	598
DOI - pysyväislinkit	https://doi.org/10.1016/S0022-328X(99)00711-1
Tila	Julkaistu - 2000
OKM-julkaisutyyppi	A1 Julkaistu artikkeli, soviteltu

Tutkimusalat

ligands
phosphine
synthesis
thioanyldichlorophosphine

Pääsy asiakirjaan

10.1016/S0022-328X(99)00711-1

2-Thioanisyldichlorophosphine_new_starting_materiaAccepted author manuscript, 127 KBLisenssi: CC BY-NC-ND

Sormenjälki Sukella tutkimusaiheisiin '2-Thioanyldichlorophosphine, new starting material for the preparation of multidentate phosphine ligands: syntheses and characterisation of derivatives of 2-anisyl- and 2-thioanisyldichlorophosphines'. Ne muodostavat yhdessä ainutlaatuisen sormenjäljen.

Siteeraa tätä

Laitinen, R. H., Heikkinen, V., Haukka, M., Koskinen, A. M. P., & Pursiainen, J. (2000). 2-Thioanyldichlorophosphine, new starting material for the preparation of multidentate phosphine ligands: syntheses and characterisation of derivatives of 2-anisyl- and 2-thioanisyldichlorophosphines. Journal of Organometallic Chemistry, (598), 235-242. https://doi.org/10.1016/S0022-328X(99)00711-1

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title = "2-Thioanyldichlorophosphine, new starting material for the preparation of multidentate phosphine ligands: syntheses and characterisation of derivatives of 2-anisyl- and 2-thioanisyldichlorophosphines",

abstract = "A new aryldichlorophosphine, 2-thioanisyldichlorophosphine, and its anisyl analogue, 2-anisyldichlorophosphine, were prepared by using an organozinc halide reagent of 2-thioanisole or 2-anisole with ethereal solution of PCl3 in refluxing conditions. From these aryldichlorophosphines, eight new multidentate phosphine ligands containing 2-thioanisyl, 4-thioanisyl, 2-anisyl, 1-naphthyl and 9-anthracenyl groups were synthesized and characterized. Characterization was based mainly on NMR spectroscopy and X-ray crystallography. The crystal structures of six ligands are reported. The electronic effects on basicity of ligandsare discussed.",

keywords = "ligands, phosphine, synthesis, thioanyldichlorophosphine, ligands, phosphine, synthesis, thioanyldichlorophosphine, ligands, phosphine, synthesis, thioanyldichlorophosphine",

author = "R.H Laitinen and V. Heikkinen and M. Haukka and A.M.P. Koskinen and J. Pursiainen",

year = "2000",

doi = "10.1016/S0022-328X(99)00711-1",

language = "English",

pages = "235--242",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

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Laitinen, RH, Heikkinen, V, Haukka, M, Koskinen, AMP & Pursiainen, J 2000, '2-Thioanyldichlorophosphine, new starting material for the preparation of multidentate phosphine ligands: syntheses and characterisation of derivatives of 2-anisyl- and 2-thioanisyldichlorophosphines', Journal of Organometallic Chemistry, Nro 598, Sivut 235-242. https://doi.org/10.1016/S0022-328X(99)00711-1

2-Thioanyldichlorophosphine, new starting material for the preparation of multidentate phosphine ligands: syntheses and characterisation of derivatives of 2-anisyl- and 2-thioanisyldichlorophosphines. / Laitinen, R.H; Heikkinen, V.; Haukka, M.; Koskinen, A.M.P.; Pursiainen, J.

julkaisussa: Journal of Organometallic Chemistry, Nro 598, 2000, s. 235-242.

Tutkimustuotos: Lehtiartikkeli › Article › Scientific › vertaisarvioitu

TY - JOUR

T1 - 2-Thioanyldichlorophosphine, new starting material for the preparation of multidentate phosphine ligands: syntheses and characterisation of derivatives of 2-anisyl- and 2-thioanisyldichlorophosphines

AU - Laitinen, R.H

AU - Heikkinen, V.

AU - Haukka, M.

AU - Koskinen, A.M.P.

AU - Pursiainen, J.

PY - 2000

Y1 - 2000

N2 - A new aryldichlorophosphine, 2-thioanisyldichlorophosphine, and its anisyl analogue, 2-anisyldichlorophosphine, were prepared by using an organozinc halide reagent of 2-thioanisole or 2-anisole with ethereal solution of PCl3 in refluxing conditions. From these aryldichlorophosphines, eight new multidentate phosphine ligands containing 2-thioanisyl, 4-thioanisyl, 2-anisyl, 1-naphthyl and 9-anthracenyl groups were synthesized and characterized. Characterization was based mainly on NMR spectroscopy and X-ray crystallography. The crystal structures of six ligands are reported. The electronic effects on basicity of ligandsare discussed.

AB - A new aryldichlorophosphine, 2-thioanisyldichlorophosphine, and its anisyl analogue, 2-anisyldichlorophosphine, were prepared by using an organozinc halide reagent of 2-thioanisole or 2-anisole with ethereal solution of PCl3 in refluxing conditions. From these aryldichlorophosphines, eight new multidentate phosphine ligands containing 2-thioanisyl, 4-thioanisyl, 2-anisyl, 1-naphthyl and 9-anthracenyl groups were synthesized and characterized. Characterization was based mainly on NMR spectroscopy and X-ray crystallography. The crystal structures of six ligands are reported. The electronic effects on basicity of ligandsare discussed.

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KW - thioanyldichlorophosphine

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KW - thioanyldichlorophosphine

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U2 - 10.1016/S0022-328X(99)00711-1

DO - 10.1016/S0022-328X(99)00711-1

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JO - Journal of Organometallic Chemistry

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