Vibrations of the interstitial oxygen pairs in silicon

M. Pesola, J. von Boehm, R.M. Nieminen

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First-principles methods are used to calculate the structures and local vibrational modes of interstitial oxygen pairs in silicon. The staggered Oi−Si−Oi and skewed Oi−Si−Si−Oi structures are nearly degenerate in energy. The calculated local vibration frequencies and their pure and mixed 18O→16O isotopic shifts agree closely with experiments: the highest frequency is assigned to the skewed and the four lower ones to the staggered structure. This result may clear up the controversy of oxygen dimers in silicon, and also suggests a mechanism for fast oxygen diffusion.
Original languageEnglish
Pages (from-to)4022-4025
JournalPhysical Review Letters
Issue number20
Publication statusPublished - 1999
MoE publication typeA1 Journal article-refereed


  • oxygen defects
  • silicon
  • vibration

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