Vapour–liquid–solid growth of monolayer MoS2 nanoribbons

Shisheng Li*, Yung Chang Lin, Wen Zhao, Jing Wu, Zhuo Wang, Zehua Hu, Youde Shen, Dai Ming Tang, Junyong Wang, Qi Zhang, Hai Zhu, Leiqiang Chu, Weijie Zhao, Chang Liu, Zhipei Sun, Takaaki Taniguchi, Minoru Osada, Wei Chen, Qing Hua Xu, Andrew Thye Shen WeeKazu Suenaga, Feng Ding, Goki Eda

*Corresponding author for this work

Research output: Contribution to journalArticleScientificpeer-review

77 Citations (Scopus)

Abstract

Chemical vapour deposition of two-dimensional materials typically involves the conversion of vapour precursors to solid products in a vapour–solid–solid mode. Here, we report the vapour–liquid–solid growth of monolayer MoS2, yielding highly crystalline ribbons with a width of few tens to thousands of nanometres. This vapour–liquid–solid growth is triggered by the reaction between MoO3 and NaCl, which results in the formation of molten Na–Mo–O droplets. These droplets mediate the growth of MoS2 ribbons in the ‘crawling mode’ when saturated with sulfur. The locally well-defined orientations of the ribbons reveal the regular horizontal motion of the droplets during growth. Using atomic-resolution scanning transmission electron microscopy and second harmonic generation microscopy, we show that the ribbons are grown homoepitaxially on monolayer MoS2 with predominantly 2H- or 3R-type stacking. Our findings highlight the prospects for the controlled growth of atomically thin nanostructure arrays for nanoelectronic devices and the development of unique mixed-dimensional structures.

Original languageEnglish
Pages (from-to)535–542
Number of pages9
JournalNature Materials
Volume17
Early online date23 Apr 2018
DOIs
Publication statusPublished - 2018
MoE publication typeA1 Journal article-refereed

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  • Projects

    Finnish Centre of Excellence in Quantum Technology

    Sun, Z., Turunen, M., Wang, Y., Du, L., Bai, X. & Cui, X.

    01/01/201819/05/2020

    Project: Academy of Finland: Other research funding

    Cite this

    Li, S., Lin, Y. C., Zhao, W., Wu, J., Wang, Z., Hu, Z., ... Eda, G. (2018). Vapour–liquid–solid growth of monolayer MoS2 nanoribbons. Nature Materials, 17, 535–542. https://doi.org/10.1038/s41563-018-0055-z