Use of convolution voltammetry for the determination of single-ion Gibbs free energy of transfer

Research output: Contribution to journalArticleScientificpeer-review


Research units

  • Helsinki University of Technology
  • University of Liverpool


Convolution cyclic voltammetry has been extended to the analysis of the case
of mixed trace/binary electrolyte diffusion and this technique has been applied
to the determination of the standard Gibbs energy of transfer of the Rb+ ion between water and 1,2-dichIoroethane. It is shown that this method gives accurate results.


Original languageEnglish
Pages (from-to)819-822
Number of pages4
JournalJournal of the Chemical Society, Faraday Transactions
Issue number5
Publication statusPublished - 1990
MoE publication typeA1 Journal article-refereed

    Research areas

  • convolution, liquid-liquid, electrochemistry

ID: 16402100