Understanding the mechanisms of oxygen diffusion through surface functionalized nanocellulose films

Maria Soledad Peresin, Kari Kammiovirta, Harri Heikkinen, Leena-Sisko Johansson, Jari Vartiainen, Harri Setälä, Monika Österberg, Tekla Tammelin*

*Corresponding author for this work

Research output: Contribution to journalArticleScientificpeer-review

33 Citations (Scopus)


A concept for direct surface modification on self-standing films of cellulose nanofibrils (CNF) is demonstrated using an aminosilane group in cellulose compatible solvent (dimethyl acetamide, DMA). The chemically modified structure efficiently prevents the oxygen molecules from interacting with the nanocellulose film in the presence of water molecules. Oxygen permeability values lower than 1 mL mm m−2 day−1 atm−1 were achieved at extremely high levels of relative humidity (RH95%). The aminosilane reaction is compared to conventional hydrophobization reaction using hexamethyldisilazane. The differences with respect to interactions between cellulosic nanofibrils, water and oxygen molecules taking place with aminated and silylated CNF films correlated with the degree of surface substitution, surface hydrophilicity and permeability of the formed layer. The self-condensation reactions taking place on the film surface during aminosilane-mediated bonding were decisive for low oxygen permeability. Experimental evidence on the importance of interfacial processes that hinder the water-cellulose interactions while keeping film's low affinity towards oxygen is demonstrated.

Original languageEnglish
Pages (from-to)309-317
Number of pages9
JournalCarbohydrate Polymers
Publication statusPublished - 15 Oct 2017
MoE publication typeA1 Journal article-refereed


  • Aminosilane reaction
  • Cellulose nanofibrils
  • CNF film
  • Oxygen permeability
  • Relative humidity
  • Surface functionalization


Dive into the research topics of 'Understanding the mechanisms of oxygen diffusion through surface functionalized nanocellulose films'. Together they form a unique fingerprint.

Cite this