The inherent structural instability: concentration-dependent transformation of pyrogallarene to pyrogallarene lactones

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The inherent structural instability: concentration-dependent transformation of pyrogallarene to pyrogallarene lactones. / Kalenius, Elina; Beyeh, Ngong Kodiah; Jänis, Janne; Rissanen, Kari.

In: Chemical Communications, Vol. 47, No. 9, 01.2011, p. 2649-2651.

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Kalenius, Elina ; Beyeh, Ngong Kodiah ; Jänis, Janne ; Rissanen, Kari. / The inherent structural instability: concentration-dependent transformation of pyrogallarene to pyrogallarene lactones. In: Chemical Communications. 2011 ; Vol. 47, No. 9. pp. 2649-2651.

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@article{30fca01f707d40cc86c72065ef40dbbd,
title = "The inherent structural instability: concentration-dependent transformation of pyrogallarene to pyrogallarene lactones",
abstract = "Pyrogallarene shows concentration-dependent instability in dilute solutions resulting in elimination of two ketene molecules and formation of pyrogallarene lactones. This unexpected phenomenon, which is not observed with resorcinarenes, highlights the significance of the four hydroxyl groups at 2-position for the molecular characteristics of pyrogallarenes.",
author = "Elina Kalenius and Beyeh, {Ngong Kodiah} and Janne J{\"a}nis and Kari Rissanen",
year = "2011",
month = "1",
doi = "10.1039/C0CC05280A",
language = "English",
volume = "47",
pages = "2649--2651",
journal = "Chemical Communications",
issn = "1359-7345",
number = "9",

}

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TY - JOUR

T1 - The inherent structural instability: concentration-dependent transformation of pyrogallarene to pyrogallarene lactones

AU - Kalenius, Elina

AU - Beyeh, Ngong Kodiah

AU - Jänis, Janne

AU - Rissanen, Kari

PY - 2011/1

Y1 - 2011/1

N2 - Pyrogallarene shows concentration-dependent instability in dilute solutions resulting in elimination of two ketene molecules and formation of pyrogallarene lactones. This unexpected phenomenon, which is not observed with resorcinarenes, highlights the significance of the four hydroxyl groups at 2-position for the molecular characteristics of pyrogallarenes.

AB - Pyrogallarene shows concentration-dependent instability in dilute solutions resulting in elimination of two ketene molecules and formation of pyrogallarene lactones. This unexpected phenomenon, which is not observed with resorcinarenes, highlights the significance of the four hydroxyl groups at 2-position for the molecular characteristics of pyrogallarenes.

U2 - 10.1039/C0CC05280A

DO - 10.1039/C0CC05280A

M3 - Article

VL - 47

SP - 2649

EP - 2651

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 9

ER -

ID: 11468189