The Effect of the Redox Potential of Aqua Regia and Temperature on the Au, Cu, and Fe Dissolution from WPCBs

Heini Elomaa, Sipi Seisko, Tero Junnila, Tuomas Sirviö, Benjamin Wilson, Jari Aromaa, Mari Lundström

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Abstract

Constant growth in waste electrical and electronic equipment (WEEE) levels necessitates the development of new, commercially viable recycling processes. Waste printed circuit boards (WPCBs) are a sub-group of WEEE that are of increasing interest due to their relatively high level of valuable metal content including Au, Ag, and platinum group metals (PGMs). Currently, precious metals like gold are mainly recycled from WEEE streams through copper melting/refining; however, the possibility to peel gold from WPCBs prior to smelting, could offer advantages for recycling. In this study, the suitability of aqua regia for selective or partially selective gold leaching from un-crushed WPCBs was investigated. The redox potential of aqua regia solutions and the dissolution efficiencies of Au, Cu, and Fe from WPCBs were investigated at different temperatures (40–80 °C) and concentrations (2–32%) in batch leaching tests. The redox potential of aqua regia solution was found to depend on concentration and temperature. It is suggested that Au dissolution in aqua regiarequires dissolved Cu2+ ions originating from the WPCB material to work. Au extraction (>50%) was shown to require a redox potential >700 mV with [Cu2+] > 2500 ppm, as a potential >850 mV alone was insufficient without cupric ions. Significant amounts of Au and Cu could be dissolved with only minor Fe dissolution at >8% aqua regia at 80 °C. Results suggest that leaching of uncrushed WPCBs in 8% aqua regia (T = 80 °C) can provide the opportunity for partial Au recovery prior to further processing.
Original languageEnglish
Number of pages9
JournalRecycling
Volume2
Issue number14
DOIs
Publication statusPublished - 1 Sep 2017
MoE publication typeA1 Journal article-refereed
EventQuo Vadis Recycling - Nový Smokovec, Slovakia
Duration: 9 Jun 20179 Jun 2017
Conference number: 6

Keywords

  • waste printed circuit boards (WPCBs)
  • Gold leaching
  • Copper leaching

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  • Projects

    NoWASTE: Novel Precious Metal Recovery from Waste Streams

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    01/09/201631/12/2020

    Project: Academy of Finland: Other research funding

    CMEco: Circular Metal Ecosystem

    Aji, A., Kalliomäki, T., Seisko, S., Leikola, M., Jafari, S., Peng, C., Agarwal, V., Elomaa, H., Hamuyuni, J., Khalid, M. K., Lundström, M., Halli, P., Sinisalo, P., Wilson, B., Revitzer, H., Partinen, J. & Wang, Z.

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    Project: Business Finland: Other research funding

    CLEEN / ARVI COR

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    Project: Business Finland: Strategic centres for science, technology and innovation (SHOK)

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