Tetranitroresorcin[4]arene: synthesis and structure of a new stereoisomer

Ngong Kodiah Beyeh; Kari Rissanen

doi:10.1016/j.tetlet.2009.10.075

Tetranitroresorcin[4]arene: synthesis and structure of a new stereoisomer

Ngong Kodiah Beyeh, Kari Rissanen

Not published at Aalto University

University of Jyväskylä

Research output: Contribution to journal › Article › Scientific › peer-review

7 Citations (Scopus)

Abstract

The direct reaction between 2-nitroresorcinol and acetaldehyde in alkaline medium yields tetranitro-C1-resorcin[4]arene in a moderate 8.2% overall yield which was characterized by single crystal X-ray crystallography, 1H NMR spectroscopy and electrospray ionization mass spectrometry (ESI-MS). In solution and in the solid state, the product adopts a unique, thermally stable and unprecedented rcct-boat conformation.

Original language	English
Pages (from-to)	7369–7373
Journal	Tetrahedron Letters
Volume	50
Issue number	52
DOIs	https://doi.org/10.1016/j.tetlet.2009.10.075
Publication status	Published - Dec 2009
MoE publication type	A1 Journal article-refereed

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title = "Tetranitroresorcin[4]arene: synthesis and structure of a new stereoisomer",

abstract = "The direct reaction between 2-nitroresorcinol and acetaldehyde in alkaline medium yields tetranitro-C1-resorcin[4]arene in a moderate 8.2% overall yield which was characterized by single crystal X-ray crystallography, 1H NMR spectroscopy and electrospray ionization mass spectrometry (ESI-MS). In solution and in the solid state, the product adopts a unique, thermally stable and unprecedented rcct-boat conformation.",

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year = "2009",

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AU - Beyeh, Ngong Kodiah

AU - Rissanen, Kari

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AB - The direct reaction between 2-nitroresorcinol and acetaldehyde in alkaline medium yields tetranitro-C1-resorcin[4]arene in a moderate 8.2% overall yield which was characterized by single crystal X-ray crystallography, 1H NMR spectroscopy and electrospray ionization mass spectrometry (ESI-MS). In solution and in the solid state, the product adopts a unique, thermally stable and unprecedented rcct-boat conformation.

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JO - Tetrahedron Letters

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Tetranitroresorcin[4]arene: synthesis and structure of a new stereoisomer

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