Ternary and binary LLE measurements for solvent (2-methyltetrahydrofuran and cyclopentyl methyl ether) + furfural + water between 298 and 343 K

Mikael Männistö; Juha Pekka Pokki; Ludivine Fournis; Ville Alopaeus

doi:10.1016/j.jct.2017.02.016

Ternary and binary LLE measurements for solvent (2-methyltetrahydrofuran and cyclopentyl methyl ether) + furfural + water between 298 and 343 K

Mikael Männistö^*, Juha Pekka Pokki, Ludivine Fournis, Ville Alopaeus

^*Corresponding author for this work

École nationale supérieure d'électrotechnique, d'électronique, d'informatique, d'hydraulique et des télécommunications

Research output: Contribution to journal › Article › Scientific › peer-review

22 Citations (Scopus)

Abstract

The suitability of two solvents for the extraction of furfural from aqueous streams is assessed through novel ternary and binary liquid-liquid equilibria data for mixtures of solvent (2-methyltetrahydrofuran or cyclopentyl methyl ether) + furfural + water. The measured data are reported along with regressed binary interaction parameters for UNIQUAC-HOC activity coefficient model and further analyzed through distribution coefficients and selectivity for furfural. Out of the two solvents, cyclopentyl methyl ether presents a very high selectivity along with good distribution coefficient in the entire temperature range.

Original language	English
Pages (from-to)	127-136
Number of pages	10
Journal	Journal of Chemical Thermodynamics
Volume	110
DOIs	https://doi.org/10.1016/j.jct.2017.02.016
Publication status	Published - 1 Jul 2017
MoE publication type	A1 Journal article-refereed

Keywords

2-Methyltetrahydrofuran
Cyclopentyl methyl ether
Equilibria
Furfural
Liquid-liquid extraction
LLE

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10.1016/j.jct.2017.02.016

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title = "Ternary and binary LLE measurements for solvent (2-methyltetrahydrofuran and cyclopentyl methyl ether) + furfural + water between 298 and 343 K",

abstract = "The suitability of two solvents for the extraction of furfural from aqueous streams is assessed through novel ternary and binary liquid-liquid equilibria data for mixtures of solvent (2-methyltetrahydrofuran or cyclopentyl methyl ether) + furfural + water. The measured data are reported along with regressed binary interaction parameters for UNIQUAC-HOC activity coefficient model and further analyzed through distribution coefficients and selectivity for furfural. Out of the two solvents, cyclopentyl methyl ether presents a very high selectivity along with good distribution coefficient in the entire temperature range.",

keywords = "2-Methyltetrahydrofuran, Cyclopentyl methyl ether, Equilibria, Furfural, Liquid-liquid extraction, LLE",

author = "Mikael M{\"a}nnist{\"o} and Pokki, {Juha Pekka} and Ludivine Fournis and Ville Alopaeus",

year = "2017",

month = jul,

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doi = "10.1016/j.jct.2017.02.016",

language = "English",

volume = "110",

pages = "127--136",

journal = "Journal of Chemical Thermodynamics",

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T1 - Ternary and binary LLE measurements for solvent (2-methyltetrahydrofuran and cyclopentyl methyl ether) + furfural + water between 298 and 343 K

AU - Männistö, Mikael

AU - Pokki, Juha Pekka

AU - Fournis, Ludivine

AU - Alopaeus, Ville

PY - 2017/7/1

Y1 - 2017/7/1

N2 - The suitability of two solvents for the extraction of furfural from aqueous streams is assessed through novel ternary and binary liquid-liquid equilibria data for mixtures of solvent (2-methyltetrahydrofuran or cyclopentyl methyl ether) + furfural + water. The measured data are reported along with regressed binary interaction parameters for UNIQUAC-HOC activity coefficient model and further analyzed through distribution coefficients and selectivity for furfural. Out of the two solvents, cyclopentyl methyl ether presents a very high selectivity along with good distribution coefficient in the entire temperature range.

AB - The suitability of two solvents for the extraction of furfural from aqueous streams is assessed through novel ternary and binary liquid-liquid equilibria data for mixtures of solvent (2-methyltetrahydrofuran or cyclopentyl methyl ether) + furfural + water. The measured data are reported along with regressed binary interaction parameters for UNIQUAC-HOC activity coefficient model and further analyzed through distribution coefficients and selectivity for furfural. Out of the two solvents, cyclopentyl methyl ether presents a very high selectivity along with good distribution coefficient in the entire temperature range.

KW - 2-Methyltetrahydrofuran

KW - Cyclopentyl methyl ether

KW - Equilibria

KW - Furfural

KW - Liquid-liquid extraction

KW - LLE

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U2 - 10.1016/j.jct.2017.02.016

DO - 10.1016/j.jct.2017.02.016

M3 - Article

AN - SCOPUS:85014530350

SN - 0021-9614

VL - 110

SP - 127

EP - 136

JO - Journal of Chemical Thermodynamics

JF - Journal of Chemical Thermodynamics

ER -

Ternary and binary LLE measurements for solvent (2-methyltetrahydrofuran and cyclopentyl methyl ether) + furfural + water between 298 and 343 K

Abstract

Keywords

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Ternary and binary LLE measurements for solvent (2-methyltetrahydrofuran and cyclopentyl methyl ether) + furfural + water between 298 and 343 K

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

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Bioeconomy Research Infrastructure

Cite this