Template-controlled synthesis of chiral cyclohexylhemicucurbit[8]uril

E. Prigorchenko; M. Öeren; S. Kaabel; M. Fomitšenko; I. Reile; I. Järving; T. Tamm; F. Topić; K. Rissanen; R. Aav

doi:10.1039/c5cc04101e

Template-controlled synthesis of chiral cyclohexylhemicucurbit[8]uril

E. Prigorchenko, M. Öeren, S. Kaabel, M. Fomitšenko, I. Reile, I. Järving, T. Tamm, F. Topić, K. Rissanen, R. Aav^*

^*Corresponding author for this work

Not published at Aalto University

Research output: Contribution to journal › Article › Scientific › peer-review

31 Citations (Scopus)

Abstract

Enantiomerically pure cyclohexylhemicucurbit[8]uril (cycHC[8]), possessing a barrel-shaped cavity, has been prepared in high yield on a gram scale from either (R,R,N,N′)-cyclohex-1,2-diylurea and formaldehyde or cycHC[6]. In either case, a dynamic covalent library is first generated from which the desired cycHC can be amplified using a suitable anion template.

Original language	English
Pages (from-to)	10921-10924
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	54
DOIs	https://doi.org/10.1039/c5cc04101e
Publication status	Published - 11 Jul 2015
MoE publication type	A1 Journal article-refereed

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title = "Template-controlled synthesis of chiral cyclohexylhemicucurbit[8]uril",

abstract = "Enantiomerically pure cyclohexylhemicucurbit[8]uril (cycHC[8]), possessing a barrel-shaped cavity, has been prepared in high yield on a gram scale from either (R,R,N,N′)-cyclohex-1,2-diylurea and formaldehyde or cycHC[6]. In either case, a dynamic covalent library is first generated from which the desired cycHC can be amplified using a suitable anion template.",

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language = "English",

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T1 - Template-controlled synthesis of chiral cyclohexylhemicucurbit[8]uril

AU - Prigorchenko, E.

AU - Öeren, M.

AU - Kaabel, S.

AU - Fomitšenko, M.

AU - Reile, I.

AU - Järving, I.

AU - Tamm, T.

AU - Topić, F.

AU - Rissanen, K.

AU - Aav, R.

PY - 2015/7/11

Y1 - 2015/7/11

N2 - Enantiomerically pure cyclohexylhemicucurbit[8]uril (cycHC[8]), possessing a barrel-shaped cavity, has been prepared in high yield on a gram scale from either (R,R,N,N′)-cyclohex-1,2-diylurea and formaldehyde or cycHC[6]. In either case, a dynamic covalent library is first generated from which the desired cycHC can be amplified using a suitable anion template.

AB - Enantiomerically pure cyclohexylhemicucurbit[8]uril (cycHC[8]), possessing a barrel-shaped cavity, has been prepared in high yield on a gram scale from either (R,R,N,N′)-cyclohex-1,2-diylurea and formaldehyde or cycHC[6]. In either case, a dynamic covalent library is first generated from which the desired cycHC can be amplified using a suitable anion template.

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U2 - 10.1039/c5cc04101e

DO - 10.1039/c5cc04101e

M3 - Article

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SP - 10921

EP - 10924

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 54

ER -

Template-controlled synthesis of chiral cyclohexylhemicucurbit[8]uril

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