Synthesis, crystal structure and NMR investigation of a new type of cyclic steroidal dimer based on brassinosteroids

Vladimir A. Khripach, Vladimir N. Zhabinskii*, Olga V. Konstantinova, Dmitrii V. Tsavlovskii, Alexander V. Baranovsky, Alexander S. Lyakhov, Pavel Drašar

*Corresponding author for this work

Research output: Contribution to journalArticleScientificpeer-review

2 Citations (Scopus)

Abstract

A new type of cyclic steroidal dimer based on brassinosteroids has been synthesized via the reaction of 24-epibrassinolide with 1,4-phenylenediboronic acid and structurally characterized by single-crystal X-ray diffraction and 2D NMR analysis. The crystal structure of the dimer was found to contain rather large solvent accessible voids.

Original languageEnglish
Pages (from-to)1-4
Number of pages4
JournalJOURNAL OF MOLECULAR STRUCTURE
Volume1032
DOIs
Publication statusPublished - 30 Jan 2013
MoE publication typeA1 Journal article-refereed

Keywords

  • Boronates
  • Brassinosteroids
  • Dimeric steroids
  • X-ray analysis

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    Khripach, V. A., Zhabinskii, V. N., Konstantinova, O. V., Tsavlovskii, D. V., Baranovsky, A. V., Lyakhov, A. S., & Drašar, P. (2013). Synthesis, crystal structure and NMR investigation of a new type of cyclic steroidal dimer based on brassinosteroids. JOURNAL OF MOLECULAR STRUCTURE, 1032, 1-4. https://doi.org/10.1016/j.molstruc.2012.07.001