Synthesis, crystal structure and NMR investigation of a new type of cyclic steroidal dimer based on brassinosteroids

Vladimir A. Khripach; Vladimir N. Zhabinskii; Olga V. Konstantinova; Dmitrii V. Tsavlovskii; Alexander V. Baranovsky; Alexander S. Lyakhov; Pavel Drašar

doi:10.1016/j.molstruc.2012.07.001

Synthesis, crystal structure and NMR investigation of a new type of cyclic steroidal dimer based on brassinosteroids

Vladimir A. Khripach, Vladimir N. Zhabinskii^*, Olga V. Konstantinova, Dmitrii V. Tsavlovskii, Alexander V. Baranovsky, Alexander S. Lyakhov, Pavel Drašar

^*Corresponding author for this work

Not published at Aalto University

Research output: Contribution to journal › Article › Scientific › peer-review

3 Citations (Scopus)

Abstract

A new type of cyclic steroidal dimer based on brassinosteroids has been synthesized via the reaction of 24-epibrassinolide with 1,4-phenylenediboronic acid and structurally characterized by single-crystal X-ray diffraction and 2D NMR analysis. The crystal structure of the dimer was found to contain rather large solvent accessible voids.

Original language	English
Pages (from-to)	1-4
Number of pages	4
Journal	JOURNAL OF MOLECULAR STRUCTURE
Volume	1032
DOIs	https://doi.org/10.1016/j.molstruc.2012.07.001
Publication status	Published - 30 Jan 2013
MoE publication type	A1 Journal article-refereed

Keywords

Boronates
Brassinosteroids
Dimeric steroids
X-ray analysis

Access to Document

10.1016/j.molstruc.2012.07.001

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title = "Synthesis, crystal structure and NMR investigation of a new type of cyclic steroidal dimer based on brassinosteroids",

abstract = "A new type of cyclic steroidal dimer based on brassinosteroids has been synthesized via the reaction of 24-epibrassinolide with 1,4-phenylenediboronic acid and structurally characterized by single-crystal X-ray diffraction and 2D NMR analysis. The crystal structure of the dimer was found to contain rather large solvent accessible voids.",

keywords = "Boronates, Brassinosteroids, Dimeric steroids, X-ray analysis",

author = "Khripach, {Vladimir A.} and Zhabinskii, {Vladimir N.} and Konstantinova, {Olga V.} and Tsavlovskii, {Dmitrii V.} and Baranovsky, {Alexander V.} and Lyakhov, {Alexander S.} and Pavel Dra{\v s}ar",

year = "2013",

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language = "English",

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Synthesis, crystal structure and NMR investigation of a new type of cyclic steroidal dimer based on brassinosteroids. / Khripach, Vladimir A.; Zhabinskii, Vladimir N.; Konstantinova, Olga V.; Tsavlovskii, Dmitrii V.; Baranovsky, Alexander V.; Lyakhov, Alexander S.; Drašar, Pavel.

In: JOURNAL OF MOLECULAR STRUCTURE, Vol. 1032, 30.01.2013, p. 1-4.

Research output: Contribution to journal › Article › Scientific › peer-review

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AU - Khripach, Vladimir A.

AU - Zhabinskii, Vladimir N.

AU - Konstantinova, Olga V.

AU - Tsavlovskii, Dmitrii V.

AU - Baranovsky, Alexander V.

AU - Lyakhov, Alexander S.

AU - Drašar, Pavel

PY - 2013/1/30

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KW - Boronates

KW - Brassinosteroids

KW - Dimeric steroids

KW - X-ray analysis

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