Synthesis and molecular structure of (n5-pentamethyl-cyclopentadienyl) (n5-cyclopentadienyl) hexacarbonyl molybdenum tungsten

Thomas Straub, Matti Haukka, Martin Brunner, Ari M.P. Koskinen, Tapani A. Pakkanen

    Research output: Contribution to journalArticleScientificpeer-review

    2 Citations (Scopus)
    21 Downloads (Pure)

    Abstract

    The metathesis reaction of Cp*(CO)3MoBr and NaW(CO)3Cp produced Cp*(CO)3Mo–W(CO)3Cp (1), featuring an unsupported Mo–W bond. Exposure of solutions of 1 to light leads to the quantitative formation of the corresponding homometallic dimers. In the solid state, the title complex exhibits an anti-arrangement of the g5-cyclopentadienyl and the g5-pentamethylcyclopentadienyl ligands and six terminal carbonyls. Comparison to corresponding complexes of molybdenum and tungsten reveals that the Mo–W distance is dictated by the presence of a Cp and a Cp* ligand. This is the first time that an unsupported Mo–W single bond distance is reported.
    Original languageEnglish
    Pages (from-to)674-677
    JournalJournal of Organometallic Chemistry
    Issue number690
    Publication statusPublished - 2005
    MoE publication typeA1 Journal article-refereed

    Keywords

    • carbonyl compounds
    • hetero bimetallic complexes
    • molybdenum
    • tungsten

    Fingerprint

    Dive into the research topics of 'Synthesis and molecular structure of (n5-pentamethyl-cyclopentadienyl) (n5-cyclopentadienyl) hexacarbonyl molybdenum tungsten'. Together they form a unique fingerprint.

    Cite this