Synthesis and Characterization of the Tetrafluoridochlorates(III) A[ClF4] (A = K, Rb, Cs)

Benjamin Scheibe, Sergei I. Ivlev, Antti J. Karttunen, Florian Kraus*

*Corresponding author for this work

Research output: Contribution to journalArticleScientificpeer-review

3 Citations (Scopus)
18 Downloads (Pure)

Abstract

Single-crystalline tetrafluoridochlorates(III) A[ClF4] (A = K, Rb, Cs) were synthesized from solvolysis reactions of alkali metal fluorides in liquid chlorine trifluoride. The structures were examined by means of single-crystal X-ray diffraction. K[ClF4] crystallizes in the K[BrF4] structure type, whereas the Rb and Cs compounds crystallize in the Li[AuF4] structure type. The compounds were further characterized by Raman and IR spectroscopy. Solid-state quantum-chemical calculations with hybrid density functional methods reproduced the experimental structures and enabled the interpretation of the experimental Raman and IR spectra.

Original languageEnglish
Pages (from-to)1319-1324
Number of pages6
JournalEuropean Journal of Inorganic Chemistry
Volume2020
Issue number14
DOIs
Publication statusPublished - 16 Apr 2020
MoE publication typeA1 Journal article-refereed

Keywords

  • Chlorine
  • Density Functional Theory Calculations
  • Fluorine
  • Interhalogen Compounds

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