Structural Phase Transitions to 2D and 3D Oxygen Vacancy Patterns in a Perovskite Film Induced by Electrical and Mechanical Nanoprobing

Lide Yao, Sampo Inkinen, Hannu-Pekka Komsa, Sebastiaan van Dijken

Research output: Contribution to journalArticleScientificpeer-review

9 Citations (Scopus)
99 Downloads (Pure)

Abstract

Oxygen vacancy migration and ordering in perovskite oxides enable manipulation of material properties through changes in the cation oxidation state and the crystal lattice. In thin-films, oxygen vacancies conventionally order into equally spaced planes. Here, it is shown that the planar 2D symmetry is broken if a mechanical nanoprobe restricts the chemical lattice expansion that the vacancies generate. Using in situ scanning transmission electron microscopy, a transition from a perovskite structure to a 3D vacancy-ordered phase in an epitaxial La2/3Sr1/3MnO3-delta film during voltage pulsing under local mechanical straining is imaged. The never-before-seen ordering pattern consists of a complex network of distorted oxygen tetrahedra, pentahedra, and octahedra that, together, produce a corrugated atomic structure with lattice constants varying between 3.5 and 4.6 angstrom. The giant lattice distortions respond sensitively to strain variations, offering prospects for non-volatile nanoscale physical property control driven by voltage and gated by strain.

Original languageEnglish
Article number2006273
Number of pages9
JournalSmall
Volume17
Issue number10
DOIs
Publication statusPublished - 11 Mar 2021
MoE publication typeA1 Journal article-refereed

Keywords

  • electric&#8208
  • field control of magnetism
  • mechanical nanoprobing
  • oxygen vacancy ordering
  • perovskite oxide
  • structural phase transition
  • transmission electron microscopy

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