Stereoselective Syntheses and Reactions of Stannylated Peptides

Jan Deska, Uli Kazmaier

Research output: Contribution to journalArticleScientificpeer-review

Abstract

tannylated allyl carbonates allow the highly stereoselective synthesis of metalated peptides, which can be further modified by Stille coupling. Tin–iodine exchange generates iodinated peptides which also can be used for C[BOND]C coupling reactions. Therefore, only one stereoselective reaction is necessary to generate a wide range of different peptides in stereochemically pure form.
Original languageEnglish
Pages (from-to)4570-4573
Number of pages4
JournalAngewandte Chemie - International Edition
Volume46
Issue number24
DOIs
Publication statusPublished - 7 May 2007
MoE publication typeA1 Journal article-refereed

Keywords

  • allylation
  • cross coupling
  • palladium
  • peptide modifications
  • stannanes

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