Abstract
The knowledge of accurate hydrogen solubility values in bio-oil compounds is essential for the design and optimization of hydroprocesses relevant to biofuel industry. This work reports the solubility of hydrogen in three industrially relevant bio-oil compounds (allyl alcohol, furan, and eugenol) at temperatures from 342 to 473 K and pressures up to 16 MPa. Phase equilibrium data were acquired using a continuous flow synthetic method. The method is based on the visual observation of the bubble point using a high resolution camera. The measured solubility is modeled with Peng-Robinson EoS with classical van der Waals one fluid mixing rules.
Original language | English |
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Pages (from-to) | 406-412 |
Number of pages | 7 |
Journal | Journal of Chemical Thermodynamics |
Volume | 102 |
DOIs | |
Publication status | Published - 1 Nov 2016 |
MoE publication type | A1 Journal article-refereed |
Keywords
- Continuous flow apparatus
- HDO
- Renewable fuels
- VLE