Solubility of hydrogen in bio-oil compounds

Muhammad Saad Qureshi*, Jouni Touronen, Petri Uusi-Kyyny, Dominique Richon, Ville Alopaeus

*Corresponding author for this work

Research output: Contribution to journalArticleScientificpeer-review

7 Citations (Scopus)

Abstract

The knowledge of accurate hydrogen solubility values in bio-oil compounds is essential for the design and optimization of hydroprocesses relevant to biofuel industry. This work reports the solubility of hydrogen in three industrially relevant bio-oil compounds (allyl alcohol, furan, and eugenol) at temperatures from 342 to 473 K and pressures up to 16 MPa. Phase equilibrium data were acquired using a continuous flow synthetic method. The method is based on the visual observation of the bubble point using a high resolution camera. The measured solubility is modeled with Peng-Robinson EoS with classical van der Waals one fluid mixing rules.

Original languageEnglish
Pages (from-to)406-412
Number of pages7
JournalJournal of Chemical Thermodynamics
Volume102
DOIs
Publication statusPublished - 1 Nov 2016
MoE publication typeA1 Journal article-refereed

Keywords

  • Continuous flow apparatus
  • HDO
  • Renewable fuels
  • VLE

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