Rod-Like Nanoparticles with Striped and Helical Topography

Jani-Markus Malho; Maria Morits; Tina I. Löbling; Nonappa Nonappa; Johanna Majoinen; Felix H. Schacher; Olli Ikkala; André H. Gröschel

doi:10.1021/acsmacrolett.6b00645

Rod-Like Nanoparticles with Striped and Helical Topography

Jani-Markus Malho, Maria Morits, Tina I. Löbling, Nonappa Nonappa, Johanna Majoinen, Felix H. Schacher, Olli Ikkala, André H. Gröschel

Research output: Contribution to journal › Article › Scientific › peer-review

35 Citations (Scopus)

Abstract

The behavior of nanoparticles in solution is largely dominated by their shape and interaction potential. Despite considerable progress in the preparation of patchy and compartmentalized particles, access to nanoparticles with complex surface patterns and topographies remains limited. Here, we show that polyanionic brushes tethered to rod-like cellulose nanocrystals (CNCs) spontaneously develop a striped or helical topography through interpolyelectrolyte complexation with polycationic di-block copolySavemers. Using cryogenic transmission electron microscopy (cryo-TEM) and tomography (cryo-ET), we follow the complexation process and analyze the delicate 3D topography on the CNC surface. The described approach is facile and modular and can be extended to other block chemistries, nanoparticles, and surfaces, thereby providing a versatile platform toward surface-patterned particles with complex topographies and spatially arranged functional groups.

Original language	English
Pages (from-to)	1185-1190
Number of pages	6
Journal	ACS Macro Letters
Volume	5
Issue number	10
DOIs	https://doi.org/10.1021/acsmacrolett.6b00645
Publication status	Published - 2016
MoE publication type	A1 Journal article-refereed

Keywords

MICELLAR INTERPOLYELECTROLYTE COMPLEXES
CELLULOSE NANOCRYSTALS
MULTICOMPARTMENT MICELLES
NANOSTRUCTURED MATERIALS
PATCHY NANOPARTICLES
BLOCK-COPOLYMERS
PARTICLES
SHELL
POLYMERS
COLLOIDS

Access to Document

10.1021/acsmacrolett.6b00645

HYBER: The Academy of Finland's Centre of Excellence in Molecular Engineering of Biosynthetic Hybrid Materials research (2014-2019)
Ikkala, O. (Principal investigator), Morits, M. (Project Member), Rissanen, S. (Project Member), Nonappa, N. (Project Member), Sanchez Sanchez, A. (Project Member), Bertula, K. (Project Member), Cherian, T. (Project Member), Haataja, J. (Project Member), Toivonen, M. (Project Member), Poutanen, M. (Project Member), Sohrabi, F. (Project Member), Hynninen, V. (Project Member) & Myllymäki, T. (Project Member)
01/01/2017 → 31/12/2019
Project: Academy of Finland: Other research funding
ERC Ikkala (ERC)
Houbenov, N. (Project Member), Cherian, T. (Project Member), Bertula, K. (Project Member), Morits, M. (Project Member), Myllymäki, T. (Project Member), Ikkala, O. (Principal investigator), Toivonen, M. (Project Member), Sorvari, J. (Project Member), Sanchez Sanchez, A. (Project Member), Nonappa, N. (Project Member), Johansson, L.-S. (Project Member), Martikainen, L. (Project Member), McKee, J. (Project Member), Junnila, S. (Project Member), Rosilo, H. (Project Member), Gröschel, A. (Project Member) & Haataja, J. (Project Member)
01/11/2011 → 31/03/2017
Project: EU: ERC grants

Cite this

@article{12f9949440ce4126a47adb878aec2eb0,

title = "Rod-Like Nanoparticles with Striped and Helical Topography",

abstract = "The behavior of nanoparticles in solution is largely dominated by their shape and interaction potential. Despite considerable progress in the preparation of patchy and compartmentalized particles, access to nanoparticles with complex surface patterns and topographies remains limited. Here, we show that polyanionic brushes tethered to rod-like cellulose nanocrystals (CNCs) spontaneously develop a striped or helical topography through interpolyelectrolyte complexation with polycationic di-block copolySavemers. Using cryogenic transmission electron microscopy (cryo-TEM) and tomography (cryo-ET), we follow the complexation process and analyze the delicate 3D topography on the CNC surface. The described approach is facile and modular and can be extended to other block chemistries, nanoparticles, and surfaces, thereby providing a versatile platform toward surface-patterned particles with complex topographies and spatially arranged functional groups.",

keywords = "MICELLAR INTERPOLYELECTROLYTE COMPLEXES, CELLULOSE NANOCRYSTALS, MULTICOMPARTMENT MICELLES, NANOSTRUCTURED MATERIALS, PATCHY NANOPARTICLES, BLOCK-COPOLYMERS, PARTICLES, SHELL, POLYMERS, COLLOIDS",

author = "Jani-Markus Malho and Maria Morits and L{\"o}bling, {Tina I.} and Nonappa Nonappa and Johanna Majoinen and Schacher, {Felix H.} and Olli Ikkala and Gr{\"o}schel, {Andr{\'e} H.}",

year = "2016",

doi = "10.1021/acsmacrolett.6b00645",

language = "English",

volume = "5",

pages = "1185--1190",

journal = "ACS Macro Letters",

issn = "2161-1653",

publisher = "American Chemical Society",

number = "10",

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TY - JOUR

T1 - Rod-Like Nanoparticles with Striped and Helical Topography

AU - Malho, Jani-Markus

AU - Morits, Maria

AU - Löbling, Tina I.

AU - Nonappa, Nonappa

AU - Majoinen, Johanna

AU - Schacher, Felix H.

AU - Ikkala, Olli

AU - Gröschel, André H.

PY - 2016

Y1 - 2016

N2 - The behavior of nanoparticles in solution is largely dominated by their shape and interaction potential. Despite considerable progress in the preparation of patchy and compartmentalized particles, access to nanoparticles with complex surface patterns and topographies remains limited. Here, we show that polyanionic brushes tethered to rod-like cellulose nanocrystals (CNCs) spontaneously develop a striped or helical topography through interpolyelectrolyte complexation with polycationic di-block copolySavemers. Using cryogenic transmission electron microscopy (cryo-TEM) and tomography (cryo-ET), we follow the complexation process and analyze the delicate 3D topography on the CNC surface. The described approach is facile and modular and can be extended to other block chemistries, nanoparticles, and surfaces, thereby providing a versatile platform toward surface-patterned particles with complex topographies and spatially arranged functional groups.

AB - The behavior of nanoparticles in solution is largely dominated by their shape and interaction potential. Despite considerable progress in the preparation of patchy and compartmentalized particles, access to nanoparticles with complex surface patterns and topographies remains limited. Here, we show that polyanionic brushes tethered to rod-like cellulose nanocrystals (CNCs) spontaneously develop a striped or helical topography through interpolyelectrolyte complexation with polycationic di-block copolySavemers. Using cryogenic transmission electron microscopy (cryo-TEM) and tomography (cryo-ET), we follow the complexation process and analyze the delicate 3D topography on the CNC surface. The described approach is facile and modular and can be extended to other block chemistries, nanoparticles, and surfaces, thereby providing a versatile platform toward surface-patterned particles with complex topographies and spatially arranged functional groups.

KW - MICELLAR INTERPOLYELECTROLYTE COMPLEXES

KW - CELLULOSE NANOCRYSTALS

KW - MULTICOMPARTMENT MICELLES

KW - NANOSTRUCTURED MATERIALS

KW - PATCHY NANOPARTICLES

KW - BLOCK-COPOLYMERS

KW - PARTICLES

KW - SHELL

KW - POLYMERS

KW - COLLOIDS

U2 - 10.1021/acsmacrolett.6b00645

DO - 10.1021/acsmacrolett.6b00645

M3 - Article

SN - 2161-1653

VL - 5

SP - 1185

EP - 1190

JO - ACS Macro Letters

JF - ACS Macro Letters

IS - 10

ER -

Rod-Like Nanoparticles with Striped and Helical Topography

Abstract

Keywords

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Projects

HYBER: The Academy of Finland's Centre of Excellence in Molecular Engineering of Biosynthetic Hybrid Materials research (2014-2019)

ERC Ikkala (ERC)

Cite this