Projects per year
Abstract
Composites comprising vanadium-pentoxide (V2O5) and single-walled carbon nanotubes (SWCNTs) are promising components for emerging applications in optoelectronics, solar cells, chemical and electrochemical sensors, etc. We propose a novel, simple, and facile approach for SWCNT covering with V2O5 by spin coating under ambient conditions. With the hydrolysis-polycondensation of the precursor (vanadyl triisopropoxide) directly on the surface of SWCNTs, the nm-thick layer of oxide is amorphous with a work function of 4.8 eV. The material recrystallizes after thermal treatment at 600 °C, achieving the work function of 5.8 eV. The key advantages of the method are that the obtained coating is uniform with a tunable thickness and does not require vacuuming or heating during processing. We demonstrate the groundbreaking results for two V2O5/SWCNT applications: transparent electrode and cathode for Li-ion batteries. As a transparent electrode, the composite shows stable sheet resistance of 160 Ω sq−1 at a 90% transmittance (550 nm) - the best performance reported for SWCNTs doped by metal oxides. As a cathode material, the obtained specific capacity (330 mA h g−1) is the highest among all the other V2O5/SWCNT cathodes reported so far. This approach opens new horizons for the creation of the next generation of metal oxide composites for various applications, including optoelectronics and electrochemistry.
Original language | English |
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Pages (from-to) | 25817-25827 |
Number of pages | 11 |
Journal | RSC Advances |
Volume | 13 |
Issue number | 37 |
DOIs | |
Publication status | Published - 30 Aug 2023 |
MoE publication type | A1 Journal article-refereed |
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Dive into the research topics of 'Robust method for uniform coating of carbon nanotubes with V2O5 for next-generation transparent electrodes and Li-ion batteries'. Together they form a unique fingerprint.Projects
- 1 Active
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NextGenBat: Next Generation Battery Materials and Concepts
Kallio, T., Ahaliabadeh, Z., Ali, B., Llanos, P. S., Kosir, J., Pakseresht, S., Rautakorpi, A. & Wang, B.
01/04/2021 → 31/03/2024
Project: Business Finland: Strategic centres for science, technology and innovation (SHOK)
Equipment
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Raw Materials Research Infrastructure
Maarit Karppinen (Manager)
School of Chemical EngineeringFacility/equipment: Facility