Reversible Photoswitching Function in Atomic/Molecular-Layer-Deposited ZnO: Azobenzene Superlattice Thin Films

Aida Khayyami, Maarit Karppinen*

*Corresponding author for this work

Research output: Contribution to journalArticleScientificpeer-review

4 Citations (Scopus)
83 Downloads (Pure)

Abstract

We report new types of reversibly photoresponsive ZnO:azobenzene superlattice thin films fabricated through atomic/molecular-layer deposition (ALD/MLD) from diethylzinc, water, and 4,4′-azobenzene dicarboxylic acid precursors. In these ultrathin films, crystalline ZnO layers are interspersed with monomolecular photoactive azobenzene dicarboxylate layers. The thickness of the individual ZnO layers is precisely controlled by the number (m) of ALD cycles applied between two subsequent MLD cycles for the azobenzene layers; in our {[(Zn-O)m+(Zn-O2-C-C6H4-N=N-C6H4-C-O2)]n+(Zn-O)m} samples, m ranges from 0 to 240. The photoresponsive behavior of the films is demonstrated with ultraviolet-visible spectroscopy; all the films are found to be photoreactive upon 360 nm irradiation, the kinetics of the resultant trans-cis photoisomerization somewhat depending on the superlattice structure. The reversibility of the photoisomerization reaction is then confirmed with a subsequent thermal treatment. Our work thus provides proof-of-concept evidence of the suitability of the ALD/MLD technology for the implementation of photoactive moieties such as azobenzene within an inorganic matrix as an attractive new methodology for creating novel light-switchable functional materials.

Original languageEnglish
Pages (from-to)5904-5911
JournalChemistry of Materials
Volume30
Issue number17
DOIs
Publication statusPublished - 2018
MoE publication typeA1 Journal article-refereed

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  • Projects

    Novel hybrid materials by ALD/MLD: from fundamentals towards applications

    Aleksandrova, I., Medina, E., Thomas, C., Karppinen, M., Haggren, A., Tiittanen, T., Penttinen, J., Ghazy, A., Mustonen, O., Khayyami, A., Revitzer, H., Sederholm, L. & Johansson, L.

    01/09/201631/08/2020

    Project: Academy of Finland: Other research funding

    Molecular-Layer-Engineered Inorganic-Organic Hybrid Materials

    Hagen, D., Khayyami, A., Marin, G., Ghazy, A., Nisula, M., Johansson, L., Safdar, M., Krahl, F., Thomas, C., Medina, E., Tiittanen, T., Giedraityte, Z., Heiska, J., Lepikko, S., Karppinen, M., Haggren, A., Tripathi, T., Penttinen, J., Philip, A., Srivastava, D., Aleksandrova, I., Mustonen, O. & Jin, H.

    23/12/201324/05/2019

    Project: EU: ERC grants

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