Recovery of Ni as Tutton’s Salts from Simulated Battery Leach Solutions

Antti Porvali; Vivek Agarwal; Helena Angerla; Mari Lundström

doi:10.1007/978-3-030-65647-8_5

Recovery of Ni as Tutton’s Salts from Simulated Battery Leach Solutions

Antti Porvali, Vivek Agarwal, Helena Angerla, Mari Lundström^*

^*Corresponding author for this work

Metso Outotec Oyj

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › Scientific › peer-review

Abstract

Recycling of battery materials is a topic with room for improvements in the recycling of the materials present in current Li-ion and NiMH batteries. In this research, a recovery route for Ni as Tutton’s salts (M⁺2 M³⁺(SO₄)₂·xH₂O) was investigated, of which Mohr’s salt ((NH₄)₂Fe(SO₄)₂*6H₂O), a commonly utilized titration reagent, is an example. Similarly, both Ni and Co can form barely soluble compounds with NH₄ ⁺ ions in an acidic sulfate media. The behavior of battery metal Ni was investigated as a function of NH₄ ⁺ ion concentration, pH and temperature in single parameter variation experiments. Ni, along with Co, was obtained with ease at a low pH over other metals that could be considered impurities (e.g. Fe). However, the usage of NH₄ ⁺ ions carries its own problems, e.g. in the subsequent downstream processes.

Original language	English
Title of host publication	Ni-Co 2021
Subtitle of host publication	The 5th International Symposium on Nickel and Cobalt
Editors	Corby Anderson, Graeme Goodall, Sumedh Gostu, Dean Gregurek, Mari Lundström, Christina Meskers, Stuart Nicol, Esa Peuraniemi, Fiseha Tesfaye, Prabhat K. Tripathy, Shijie Wang, Yuanbo Zhang
Publisher	Springer
Pages	81-89
Number of pages	9
ISBN (Electronic)	978-3-030-65647-8
ISBN (Print)	978-3-030-65646-1
DOIs	https://doi.org/10.1007/978-3-030-65647-8_5
Publication status	Published - 2021
MoE publication type	A4 Conference publication
Event	International Symposium on Nickel and Cobalt - Virtual, Online Duration: 15 Mar 2021 → 18 Mar 2021 Conference number: 5

Publication series

Name	Minerals, Metals and Materials Series
ISSN (Print)	2367-1181
ISSN (Electronic)	2367-1696

Conference

Conference	International Symposium on Nickel and Cobalt
Abbreviated title	Ni-Co
City	Virtual, Online
Period	15/03/2021 → 18/03/2021

Keywords

Battery recycling
Precipitation
Tutton’s salts

Access to Document

10.1007/978-3-030-65647-8_5

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Porvali, A., Agarwal, V., Angerla, H., & Lundström, M. (2021). Recovery of Ni as Tutton’s Salts from Simulated Battery Leach Solutions. In C. Anderson, G. Goodall, S. Gostu, D. Gregurek, M. Lundström, C. Meskers, S. Nicol, E. Peuraniemi, F. Tesfaye, P. K. Tripathy, S. Wang, & Y. Zhang (Eds.), Ni-Co 2021: The 5th International Symposium on Nickel and Cobalt (pp. 81-89). (Minerals, Metals and Materials Series). Springer. https://doi.org/10.1007/978-3-030-65647-8_5

Porvali, Antti ; Agarwal, Vivek ; Angerla, Helena et al. / Recovery of Ni as Tutton’s Salts from Simulated Battery Leach Solutions. Ni-Co 2021: The 5th International Symposium on Nickel and Cobalt. editor / Corby Anderson ; Graeme Goodall ; Sumedh Gostu ; Dean Gregurek ; Mari Lundström ; Christina Meskers ; Stuart Nicol ; Esa Peuraniemi ; Fiseha Tesfaye ; Prabhat K. Tripathy ; Shijie Wang ; Yuanbo Zhang. Springer, 2021. pp. 81-89 (Minerals, Metals and Materials Series).

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title = "Recovery of Ni as Tutton{\textquoteright}s Salts from Simulated Battery Leach Solutions",

abstract = "Recycling of battery materials is a topic with room for improvements in the recycling of the materials present in current Li-ion and NiMH batteries. In this research, a recovery route for Ni as Tutton{\textquoteright}s salts (M+2 M3+(SO4)2·xH2O) was investigated, of which Mohr{\textquoteright}s salt ((NH4)2Fe(SO4)2*6H2O), a commonly utilized titration reagent, is an example. Similarly, both Ni and Co can form barely soluble compounds with NH4 + ions in an acidic sulfate media. The behavior of battery metal Ni was investigated as a function of NH4 + ion concentration, pH and temperature in single parameter variation experiments. Ni, along with Co, was obtained with ease at a low pH over other metals that could be considered impurities (e.g. Fe). However, the usage of NH4 + ions carries its own problems, e.g. in the subsequent downstream processes.",

keywords = "Battery recycling, Precipitation, Tutton{\textquoteright}s salts",

author = "Antti Porvali and Vivek Agarwal and Helena Angerla and Mari Lundstr{\"o}m",

note = "Funding Information: This research was funded by BATCircle (XYZ). This work also made use of RAWMatters Research Infrastructure, funded by Academy of Finland. We would like to thank Hannu Revitzer for performing the AAS analyses. Publisher Copyright: {\textcopyright} 2021, The Minerals, Metals & Materials Society. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.; International Symposium on Nickel and Cobalt, Ni-Co ; Conference date: 15-03-2021 Through 18-03-2021",

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Porvali, A, Agarwal, V, Angerla, H & Lundström, M 2021, Recovery of Ni as Tutton’s Salts from Simulated Battery Leach Solutions. in C Anderson, G Goodall, S Gostu, D Gregurek, M Lundström, C Meskers, S Nicol, E Peuraniemi, F Tesfaye, PK Tripathy, S Wang & Y Zhang (eds), Ni-Co 2021: The 5th International Symposium on Nickel and Cobalt. Minerals, Metals and Materials Series, Springer, pp. 81-89, International Symposium on Nickel and Cobalt, Virtual, Online, 15/03/2021. https://doi.org/10.1007/978-3-030-65647-8_5

Recovery of Ni as Tutton’s Salts from Simulated Battery Leach Solutions. / Porvali, Antti; Agarwal, Vivek; Angerla, Helena et al.
Ni-Co 2021: The 5th International Symposium on Nickel and Cobalt. ed. / Corby Anderson; Graeme Goodall; Sumedh Gostu; Dean Gregurek; Mari Lundström; Christina Meskers; Stuart Nicol; Esa Peuraniemi; Fiseha Tesfaye; Prabhat K. Tripathy; Shijie Wang; Yuanbo Zhang. Springer, 2021. p. 81-89 (Minerals, Metals and Materials Series).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › Scientific › peer-review

TY - GEN

T1 - Recovery of Ni as Tutton’s Salts from Simulated Battery Leach Solutions

AU - Porvali, Antti

AU - Agarwal, Vivek

AU - Angerla, Helena

AU - Lundström, Mari

N1 - Conference code: 5

PY - 2021

Y1 - 2021

N2 - Recycling of battery materials is a topic with room for improvements in the recycling of the materials present in current Li-ion and NiMH batteries. In this research, a recovery route for Ni as Tutton’s salts (M+2 M3+(SO4)2·xH2O) was investigated, of which Mohr’s salt ((NH4)2Fe(SO4)2*6H2O), a commonly utilized titration reagent, is an example. Similarly, both Ni and Co can form barely soluble compounds with NH4 + ions in an acidic sulfate media. The behavior of battery metal Ni was investigated as a function of NH4 + ion concentration, pH and temperature in single parameter variation experiments. Ni, along with Co, was obtained with ease at a low pH over other metals that could be considered impurities (e.g. Fe). However, the usage of NH4 + ions carries its own problems, e.g. in the subsequent downstream processes.

AB - Recycling of battery materials is a topic with room for improvements in the recycling of the materials present in current Li-ion and NiMH batteries. In this research, a recovery route for Ni as Tutton’s salts (M+2 M3+(SO4)2·xH2O) was investigated, of which Mohr’s salt ((NH4)2Fe(SO4)2*6H2O), a commonly utilized titration reagent, is an example. Similarly, both Ni and Co can form barely soluble compounds with NH4 + ions in an acidic sulfate media. The behavior of battery metal Ni was investigated as a function of NH4 + ion concentration, pH and temperature in single parameter variation experiments. Ni, along with Co, was obtained with ease at a low pH over other metals that could be considered impurities (e.g. Fe). However, the usage of NH4 + ions carries its own problems, e.g. in the subsequent downstream processes.

KW - Battery recycling

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BT - Ni-Co 2021

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A2 - Goodall, Graeme

A2 - Gostu, Sumedh

A2 - Gregurek, Dean

A2 - Lundström, Mari

A2 - Meskers, Christina

A2 - Nicol, Stuart

A2 - Peuraniemi, Esa

A2 - Tesfaye, Fiseha

A2 - Tripathy, Prabhat K.

A2 - Wang, Shijie

A2 - Zhang, Yuanbo

PB - Springer

T2 - International Symposium on Nickel and Cobalt

Y2 - 15 March 2021 through 18 March 2021

ER -

Porvali A, Agarwal V, Angerla H, Lundström M. Recovery of Ni as Tutton’s Salts from Simulated Battery Leach Solutions. In Anderson C, Goodall G, Gostu S, Gregurek D, Lundström M, Meskers C, Nicol S, Peuraniemi E, Tesfaye F, Tripathy PK, Wang S, Zhang Y, editors, Ni-Co 2021: The 5th International Symposium on Nickel and Cobalt. Springer. 2021. p. 81-89. (Minerals, Metals and Materials Series). doi: 10.1007/978-3-030-65647-8_5

Recovery of Ni as Tutton’s Salts from Simulated Battery Leach Solutions

Abstract

Publication series

Conference

Keywords

Access to Document

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BATCIRCLE: Finland-based Circular Ecosystem of Battery Metals

Raw Materials Research Infrastructure

Cite this

Recovery of Ni as Tutton’s Salts from Simulated Battery Leach Solutions

Abstract

Publication series

Conference

Keywords

Access to Document

OpenUrl availability

Other files and links

Fingerprint

Projects

BATCIRCLE: Finland-based Circular Ecosystem of Battery Metals

Equipment

Raw Materials Research Infrastructure

Cite this