Recovery of High-Purity MnO2 from the Acid Leaching Solution of Spent Li-Ion Batteries

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Recovery of High-Purity MnO2 from the Acid Leaching Solution of Spent Li-Ion Batteries. / Peng, Chao; Chang, Cong; Wang, Zulin; Wilson, Benjamin P.; Liu, Fupeng; Lundström, Mari.

In: JOM, 23.09.2019.

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@article{44cf85f55a53428e8091c63e801d9ca9,
title = "Recovery of High-Purity MnO2 from the Acid Leaching Solution of Spent Li-Ion Batteries",
abstract = "Hydrometallurgical recycling processes for spent Li-ion batteries (LIBs) often produce pregnant leach solutions (PLS) that contain metals like Co, Ni, Mn, Li, Al, etc. Although significant research has focused on the recovery of the most valuable materials (e.g., Co, Ni, Li), the reclamation of Mn from PLS is often neglected. In this study, recovery of Mn via a multi-step process based on solvent extraction with di-2-ethylhexyl phosphoric acid, scrubbing, stripping and oxidative Mn precipitation has been undertaken. The results demonstrate that more than 99{\%} of Mn can be successfully recovered as a high-purity MnO2 product (purity > 99.5{\%}) with almost no loss of Co, Ni and Li. In addition, the behavior of other metal elements present in the PLS were also studied in detail. Overall, this study investigates the fundamentals of Mn recovery from the complicated PLS of LIBs waste and outlines industrial process feasibility based on known unit process steps.",
keywords = "Circular economy of metals, Battery Recycling, Sustainability",
author = "Chao Peng and Cong Chang and Zulin Wang and Wilson, {Benjamin P.} and Fupeng Liu and Mari Lundstr{\"o}m",
note = "The online version of this article (https://doi.org/10.1007/s11837-019-03785-1) contains supplementary material, which is available to authorized users.",
year = "2019",
month = "9",
day = "23",
doi = "10.1007/s11837-019-03785-1",
language = "English",
journal = "JOM",
issn = "1047-4838",

}

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TY - JOUR

T1 - Recovery of High-Purity MnO2 from the Acid Leaching Solution of Spent Li-Ion Batteries

AU - Peng, Chao

AU - Chang, Cong

AU - Wang, Zulin

AU - Wilson, Benjamin P.

AU - Liu, Fupeng

AU - Lundström, Mari

N1 - The online version of this article (https://doi.org/10.1007/s11837-019-03785-1) contains supplementary material, which is available to authorized users.

PY - 2019/9/23

Y1 - 2019/9/23

N2 - Hydrometallurgical recycling processes for spent Li-ion batteries (LIBs) often produce pregnant leach solutions (PLS) that contain metals like Co, Ni, Mn, Li, Al, etc. Although significant research has focused on the recovery of the most valuable materials (e.g., Co, Ni, Li), the reclamation of Mn from PLS is often neglected. In this study, recovery of Mn via a multi-step process based on solvent extraction with di-2-ethylhexyl phosphoric acid, scrubbing, stripping and oxidative Mn precipitation has been undertaken. The results demonstrate that more than 99% of Mn can be successfully recovered as a high-purity MnO2 product (purity > 99.5%) with almost no loss of Co, Ni and Li. In addition, the behavior of other metal elements present in the PLS were also studied in detail. Overall, this study investigates the fundamentals of Mn recovery from the complicated PLS of LIBs waste and outlines industrial process feasibility based on known unit process steps.

AB - Hydrometallurgical recycling processes for spent Li-ion batteries (LIBs) often produce pregnant leach solutions (PLS) that contain metals like Co, Ni, Mn, Li, Al, etc. Although significant research has focused on the recovery of the most valuable materials (e.g., Co, Ni, Li), the reclamation of Mn from PLS is often neglected. In this study, recovery of Mn via a multi-step process based on solvent extraction with di-2-ethylhexyl phosphoric acid, scrubbing, stripping and oxidative Mn precipitation has been undertaken. The results demonstrate that more than 99% of Mn can be successfully recovered as a high-purity MnO2 product (purity > 99.5%) with almost no loss of Co, Ni and Li. In addition, the behavior of other metal elements present in the PLS were also studied in detail. Overall, this study investigates the fundamentals of Mn recovery from the complicated PLS of LIBs waste and outlines industrial process feasibility based on known unit process steps.

KW - Circular economy of metals

KW - Battery Recycling

KW - Sustainability

U2 - 10.1007/s11837-019-03785-1

DO - 10.1007/s11837-019-03785-1

M3 - Article

JO - JOM

JF - JOM

SN - 1047-4838

ER -

ID: 37077300