Quaternary, Ternary and Binary LLE Measurements for 2-Methoxy-2-methylbutane + Furfural + Acetic Acid + Water at Temperatures between 298 and 341 K

Mikael Männistö; Juha-Pekka Pokki; Hele Haapaniemi; Ville Alopaeus

doi:10.1021/acs.jced.6b00150

Quaternary, Ternary and Binary LLE Measurements for 2-Methoxy-2-methylbutane + Furfural + Acetic Acid + Water at Temperatures between 298 and 341 K

Mikael Männistö, Juha-Pekka Pokki, Hele Haapaniemi, Ville Alopaeus

Research output: Contribution to journal › Article › Scientific › peer-review

3 Citations (Scopus)

Abstract

Measured quaternary and ternary liquid–liquid equilibrium for 2-methoxy-2-methylbutane (tert-amyl methyl ether, TAME) with furfural, acetic acid, and water are presented in the temperature range between 298 and 341 K. In addition, binary pairs for TAME + water and furfural + water were measured in the range between 298 and 341 K. Results were modeled with UNIQUAC-HOC (Hayden–O’Connell) activity coefficient model and corresponding binary interaction parameters are presented along with measurement data. Solvent suitability for industrial use was assessed for 2-methoxy-2-methylbutane and compared to 2-methoxy-2-methylpropane and other industrial solvents.

Original language	English
Pages (from-to)	3730 - 3739
Number of pages	9
Journal	Journal of Chemical and Engineering Data
Volume	61
Issue number	11
DOIs	https://doi.org/10.1021/acs.jced.6b00150
Publication status	Published - 31 Oct 2016
MoE publication type	A1 Journal article-refereed

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@article{a38e53cca8184d228c4009538711b05e,

title = "Quaternary, Ternary and Binary LLE Measurements for 2-Methoxy-2-methylbutane + Furfural + Acetic Acid + Water at Temperatures between 298 and 341 K",

abstract = "Measured quaternary and ternary liquid–liquid equilibrium for 2-methoxy-2-methylbutane (tert-amyl methyl ether, TAME) with furfural, acetic acid, and water are presented in the temperature range between 298 and 341 K. In addition, binary pairs for TAME + water and furfural + water were measured in the range between 298 and 341 K. Results were modeled with UNIQUAC-HOC (Hayden–O{\textquoteright}Connell) activity coefficient model and corresponding binary interaction parameters are presented along with measurement data. Solvent suitability for industrial use was assessed for 2-methoxy-2-methylbutane and compared to 2-methoxy-2-methylpropane and other industrial solvents.",

author = "Mikael M{\"a}nnist{\"o} and Juha-Pekka Pokki and Hele Haapaniemi and Ville Alopaeus",

year = "2016",

month = oct,

day = "31",

doi = "10.1021/acs.jced.6b00150",

language = "English",

volume = "61",

pages = "3730 -- 3739",

journal = "Journal of Chemical and Engineering Data",

issn = "0021-9568",

publisher = "AMERICAN CHEMICAL SOCIETY",

number = "11",

}

Quaternary, Ternary and Binary LLE Measurements for 2-Methoxy-2-methylbutane + Furfural + Acetic Acid + Water at Temperatures between 298 and 341 K. / Männistö, Mikael; Pokki, Juha-Pekka; Haapaniemi, Hele; Alopaeus, Ville.

In: Journal of Chemical and Engineering Data, Vol. 61, No. 11, 31.10.2016, p. 3730 - 3739.

Research output: Contribution to journal › Article › Scientific › peer-review

TY - JOUR

T1 - Quaternary, Ternary and Binary LLE Measurements for 2-Methoxy-2-methylbutane + Furfural + Acetic Acid + Water at Temperatures between 298 and 341 K

AU - Männistö, Mikael

AU - Pokki, Juha-Pekka

AU - Haapaniemi, Hele

AU - Alopaeus, Ville

PY - 2016/10/31

Y1 - 2016/10/31

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AB - Measured quaternary and ternary liquid–liquid equilibrium for 2-methoxy-2-methylbutane (tert-amyl methyl ether, TAME) with furfural, acetic acid, and water are presented in the temperature range between 298 and 341 K. In addition, binary pairs for TAME + water and furfural + water were measured in the range between 298 and 341 K. Results were modeled with UNIQUAC-HOC (Hayden–O’Connell) activity coefficient model and corresponding binary interaction parameters are presented along with measurement data. Solvent suitability for industrial use was assessed for 2-methoxy-2-methylbutane and compared to 2-methoxy-2-methylpropane and other industrial solvents.

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