Press hardening of zinc-coated boron steels: Role of steel composition in the development of phase structures within coating and interface regions

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Press hardening of zinc-coated boron steels : Role of steel composition in the development of phase structures within coating and interface regions. / Järvinen, Henri; Honkanen, Mari; Patnamsetty, Madan; Järn, Sanna; Heinonen, Esa; Jiang, Hua; Peura, Pasi.

In: Surface and Coatings Technology, Vol. 352, 25.10.2018, p. 378-391.

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Järvinen, Henri ; Honkanen, Mari ; Patnamsetty, Madan ; Järn, Sanna ; Heinonen, Esa ; Jiang, Hua ; Peura, Pasi. / Press hardening of zinc-coated boron steels : Role of steel composition in the development of phase structures within coating and interface regions. In: Surface and Coatings Technology. 2018 ; Vol. 352. pp. 378-391.

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@article{95d9da9ff3344b3bb90a570b6f779f77,
title = "Press hardening of zinc-coated boron steels: Role of steel composition in the development of phase structures within coating and interface regions",
abstract = "Zn and ZnFe coated 22MnB5 and 34MnB5 steels were subjected to the direct press hardening process in order to investigate the influence of steel composition on the resulting phase structures. Microstructures were characterized using advanced methods of microscopy. In addition, X-ray diffraction, glow discharge optical emission spectroscopy and thermodynamic calculations with Thermo-Calc{\circledR} were carried out to support the analysis. The results indicate that the steel composition has a clear effect on the phase development within coating and interface regions. Whereas the behavior of the 22MnB5 was comparable to earlier investigations, a clearly non-conventional behavior of the 34MnB5 was observed: the formation of martensitic micro constituents, designated here as α′-Fe(Zn), were identified after die-quenching. The regions of the α′-Fe(Zn) formed mainly in vicinity of steel/coating interface and were emerged into the steel by sharing martensitic morphology with the base steel. The thermodynamic calculations suggest that carbon is effective in stabilizing the γ-Fe(Zn) phase, which enables the formation of the α′-Fe(Zn) in fast cooling. Therefore, the higher initial C content of the 34MnB5 may result in the kinetic stabilization of the γ-Fe(Zn) as the inter-diffusion between Zn and Fe occurs during annealing. Simultaneously occurring carbon partitioning from α-Fe(Zn) to γ-Fe(Zn) could explain a clearly increased C content of the coating/steel interface as well as higher Zn contents in the α′-Fe(Zn) phase compared to 22MnB5. Actually, the present study shows that the same phenomenon occurs also in 22MnB5 steels, but in a much smaller scale. In Zn and ZnFe coated 34MnB5, the thickness of the α′-Fe(Zn) layer was increased with longer annealing times and at higher temperatures. The morphology of the α′-Fe(Zn) layer resembled plate-like martensite and can be assumed to be brittle. Regarding this, the formation of α′-Fe(Zn) interface layer needs to be taken into account in press hardening of 34MnB5 steels.",
keywords = "Electron backscatter diffraction, Focused ion beam, Hot-dip galvanizing, Phase transformations, Press hardening, Transmission electron microscopy",
author = "Henri J{\"a}rvinen and Mari Honkanen and Madan Patnamsetty and Sanna J{\"a}rn and Esa Heinonen and Hua Jiang and Pasi Peura",
year = "2018",
month = "10",
day = "25",
doi = "10.1016/j.surfcoat.2018.08.040",
language = "English",
volume = "352",
pages = "378--391",
journal = "Surface and Coatings Technology",
issn = "0257-8972",
publisher = "Elsevier Science",

}

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TY - JOUR

T1 - Press hardening of zinc-coated boron steels

T2 - Role of steel composition in the development of phase structures within coating and interface regions

AU - Järvinen, Henri

AU - Honkanen, Mari

AU - Patnamsetty, Madan

AU - Järn, Sanna

AU - Heinonen, Esa

AU - Jiang, Hua

AU - Peura, Pasi

PY - 2018/10/25

Y1 - 2018/10/25

N2 - Zn and ZnFe coated 22MnB5 and 34MnB5 steels were subjected to the direct press hardening process in order to investigate the influence of steel composition on the resulting phase structures. Microstructures were characterized using advanced methods of microscopy. In addition, X-ray diffraction, glow discharge optical emission spectroscopy and thermodynamic calculations with Thermo-Calc® were carried out to support the analysis. The results indicate that the steel composition has a clear effect on the phase development within coating and interface regions. Whereas the behavior of the 22MnB5 was comparable to earlier investigations, a clearly non-conventional behavior of the 34MnB5 was observed: the formation of martensitic micro constituents, designated here as α′-Fe(Zn), were identified after die-quenching. The regions of the α′-Fe(Zn) formed mainly in vicinity of steel/coating interface and were emerged into the steel by sharing martensitic morphology with the base steel. The thermodynamic calculations suggest that carbon is effective in stabilizing the γ-Fe(Zn) phase, which enables the formation of the α′-Fe(Zn) in fast cooling. Therefore, the higher initial C content of the 34MnB5 may result in the kinetic stabilization of the γ-Fe(Zn) as the inter-diffusion between Zn and Fe occurs during annealing. Simultaneously occurring carbon partitioning from α-Fe(Zn) to γ-Fe(Zn) could explain a clearly increased C content of the coating/steel interface as well as higher Zn contents in the α′-Fe(Zn) phase compared to 22MnB5. Actually, the present study shows that the same phenomenon occurs also in 22MnB5 steels, but in a much smaller scale. In Zn and ZnFe coated 34MnB5, the thickness of the α′-Fe(Zn) layer was increased with longer annealing times and at higher temperatures. The morphology of the α′-Fe(Zn) layer resembled plate-like martensite and can be assumed to be brittle. Regarding this, the formation of α′-Fe(Zn) interface layer needs to be taken into account in press hardening of 34MnB5 steels.

AB - Zn and ZnFe coated 22MnB5 and 34MnB5 steels were subjected to the direct press hardening process in order to investigate the influence of steel composition on the resulting phase structures. Microstructures were characterized using advanced methods of microscopy. In addition, X-ray diffraction, glow discharge optical emission spectroscopy and thermodynamic calculations with Thermo-Calc® were carried out to support the analysis. The results indicate that the steel composition has a clear effect on the phase development within coating and interface regions. Whereas the behavior of the 22MnB5 was comparable to earlier investigations, a clearly non-conventional behavior of the 34MnB5 was observed: the formation of martensitic micro constituents, designated here as α′-Fe(Zn), were identified after die-quenching. The regions of the α′-Fe(Zn) formed mainly in vicinity of steel/coating interface and were emerged into the steel by sharing martensitic morphology with the base steel. The thermodynamic calculations suggest that carbon is effective in stabilizing the γ-Fe(Zn) phase, which enables the formation of the α′-Fe(Zn) in fast cooling. Therefore, the higher initial C content of the 34MnB5 may result in the kinetic stabilization of the γ-Fe(Zn) as the inter-diffusion between Zn and Fe occurs during annealing. Simultaneously occurring carbon partitioning from α-Fe(Zn) to γ-Fe(Zn) could explain a clearly increased C content of the coating/steel interface as well as higher Zn contents in the α′-Fe(Zn) phase compared to 22MnB5. Actually, the present study shows that the same phenomenon occurs also in 22MnB5 steels, but in a much smaller scale. In Zn and ZnFe coated 34MnB5, the thickness of the α′-Fe(Zn) layer was increased with longer annealing times and at higher temperatures. The morphology of the α′-Fe(Zn) layer resembled plate-like martensite and can be assumed to be brittle. Regarding this, the formation of α′-Fe(Zn) interface layer needs to be taken into account in press hardening of 34MnB5 steels.

KW - Electron backscatter diffraction

KW - Focused ion beam

KW - Hot-dip galvanizing

KW - Phase transformations

KW - Press hardening

KW - Transmission electron microscopy

UR - http://www.scopus.com/inward/record.url?scp=85051676954&partnerID=8YFLogxK

U2 - 10.1016/j.surfcoat.2018.08.040

DO - 10.1016/j.surfcoat.2018.08.040

M3 - Article

VL - 352

SP - 378

EP - 391

JO - Surface and Coatings Technology

JF - Surface and Coatings Technology

SN - 0257-8972

ER -

ID: 30100179