Preparation of Lithium Containing Oxides by the Solid State Reaction of Atomic Layer Deposited Thin Films

Research output: Contribution to journalArticleScientificpeer-review

Researchers

  • Elisa Atosuo
  • Miia Mäntymäki

  • Kenichiro Mizohata
  • Mikko J. Heikkilä
  • Jyrki Räisänen
  • Mikko Ritala
  • Markku Leskelä

Research units

  • University of Helsinki

Abstract

Lithium containing multicomponent oxides are important materials for both lithium-ion batteries and optical applications. In most cases thin films of these materials are desired. Atomic layer deposition (ALD) is a thin film deposition method that is known to deposit high quality films by sequential self-limiting surface reactions. However, the reactivity of lithium ions during the deposition process can pose challenges for the control of the film growth and even destroy the self-limiting nature of ALD completely. In this paper, we have studied the combination of atomic layer deposition and solid state reactions for the generation of lithium containing multicomponent oxide films. Atomic layer deposited transition metal oxide thin films were covered with ALD-grown lithium carbonate, and the films were annealed to produce lithium tantalate, titanate, and niobate. Lithium carbonate was chosen as the source of lithium because it is easy to deposit by ALD and can be handled in air. The films were analyzed as-deposited and after annealing using grazing incidence X-ray diffraction (GIXRD), field emission scanning electron microscopy (FESEM), and time-of-flight elastic recoil detection analysis (ToF-ERDA). By this method we were able to produce crystalline and very close to stoichiometric films of LiTaO3, Li2TiO3, and LiNbO3. The films showed only small amounts of carbon and hydrogen impurities after annealing. After prolonged annealing at high temperatures, lithium silicates began to form as a result of lithium ions reacting with the silicon substrates.

Details

Original languageEnglish
Pages (from-to)998-1005
Number of pages8
JournalChemistry of Materials
Volume29
Issue number3
Publication statusPublished - 14 Feb 2017
MoE publication typeA1 Journal article-refereed

ID: 28852702