Platinum recovery from Industrial Process Solutions by Electrodepo-sition-Redox Replacement

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@article{568a8df56d934957826f9b088aa77b60,
title = "Platinum recovery from Industrial Process Solutions by Electrodepo-sition-Redox Replacement",
abstract = "In the current study, platinum - present as a negligible component (below 1 ppb, the detection limit of the HR-ICP-MS at the dilutions used) in real industrial hydrometallurgical process solutions was recovered by an electrodeposition − redox replacement (EDRR) method on pyrolysed carbon (PyC) electrode, a method not earlier applied to metal recovery. The recovery parameters of the EDRR process were initially investigated using a synthetic nickel electrolyte solution ([Ni] = 60 g/L, [Ag] = 10 ppm, [Pt] = 20 ppm, [H2SO4] = 10 g/L) and the results demonstrated an extraordinary increase of 3·105 in the [Pt]/[Ni] on the electrode surface cf. synthetic solution. EDRR recovery of platinum on PyC was also tested with two real industrial process solutions that contained a complex multi-metal solution matrix: Ni as the major component (>140 g/L) and very low contents of Pt, Pd and Ag (i.e. <1 ppb, 117 ppb and 4 ppb, respectively). The selectivity of Pt recovery by EDRR on the PyC electrode was found to be significant – nanoparticles deposited on the electrode surface comprised on average of 90 wt-{\%} platinum and a [Pt]/[Ni] enrichment ratio of 1011 compared to the industrial hydrometallurgical solution. Furthermore, other precious metallic elements like Pd and Ag could also be enriched on the PyC electrode surface using the same methodology. This paper demonstrates a remarkable advancement in the recovery of trace amounts of platinum from real industrial solutions that are not currently considered as a source of Pt metal.",
keywords = "Circular Economy, Critical Precious Metals, Electrochemistry, Green Chemistry, Electrochemically Assisted Cementation",
author = "Petteri Halli and Joonas Heikkinen and Heini Elomaa and Benjamin Wilson and Ville Jokinen and Kirsi Yliniemi and Sami Franssila and Mari Lundstr{\"o}m",
year = "2018",
month = "9",
day = "20",
doi = "10.1021/ acssuschemeng.8b03224",
language = "English",
volume = "6",
pages = "14631–14640",
journal = "ACS Sustainable Chemistry and Engineering",
issn = "2168-0485",
publisher = "AMERICAN CHEMICAL SOCIETY",
number = "11",

}

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TY - JOUR

T1 - Platinum recovery from Industrial Process Solutions by Electrodepo-sition-Redox Replacement

AU - Halli, Petteri

AU - Heikkinen, Joonas

AU - Elomaa, Heini

AU - Wilson, Benjamin

AU - Jokinen, Ville

AU - Yliniemi, Kirsi

AU - Franssila, Sami

AU - Lundström, Mari

PY - 2018/9/20

Y1 - 2018/9/20

N2 - In the current study, platinum - present as a negligible component (below 1 ppb, the detection limit of the HR-ICP-MS at the dilutions used) in real industrial hydrometallurgical process solutions was recovered by an electrodeposition − redox replacement (EDRR) method on pyrolysed carbon (PyC) electrode, a method not earlier applied to metal recovery. The recovery parameters of the EDRR process were initially investigated using a synthetic nickel electrolyte solution ([Ni] = 60 g/L, [Ag] = 10 ppm, [Pt] = 20 ppm, [H2SO4] = 10 g/L) and the results demonstrated an extraordinary increase of 3·105 in the [Pt]/[Ni] on the electrode surface cf. synthetic solution. EDRR recovery of platinum on PyC was also tested with two real industrial process solutions that contained a complex multi-metal solution matrix: Ni as the major component (>140 g/L) and very low contents of Pt, Pd and Ag (i.e. <1 ppb, 117 ppb and 4 ppb, respectively). The selectivity of Pt recovery by EDRR on the PyC electrode was found to be significant – nanoparticles deposited on the electrode surface comprised on average of 90 wt-% platinum and a [Pt]/[Ni] enrichment ratio of 1011 compared to the industrial hydrometallurgical solution. Furthermore, other precious metallic elements like Pd and Ag could also be enriched on the PyC electrode surface using the same methodology. This paper demonstrates a remarkable advancement in the recovery of trace amounts of platinum from real industrial solutions that are not currently considered as a source of Pt metal.

AB - In the current study, platinum - present as a negligible component (below 1 ppb, the detection limit of the HR-ICP-MS at the dilutions used) in real industrial hydrometallurgical process solutions was recovered by an electrodeposition − redox replacement (EDRR) method on pyrolysed carbon (PyC) electrode, a method not earlier applied to metal recovery. The recovery parameters of the EDRR process were initially investigated using a synthetic nickel electrolyte solution ([Ni] = 60 g/L, [Ag] = 10 ppm, [Pt] = 20 ppm, [H2SO4] = 10 g/L) and the results demonstrated an extraordinary increase of 3·105 in the [Pt]/[Ni] on the electrode surface cf. synthetic solution. EDRR recovery of platinum on PyC was also tested with two real industrial process solutions that contained a complex multi-metal solution matrix: Ni as the major component (>140 g/L) and very low contents of Pt, Pd and Ag (i.e. <1 ppb, 117 ppb and 4 ppb, respectively). The selectivity of Pt recovery by EDRR on the PyC electrode was found to be significant – nanoparticles deposited on the electrode surface comprised on average of 90 wt-% platinum and a [Pt]/[Ni] enrichment ratio of 1011 compared to the industrial hydrometallurgical solution. Furthermore, other precious metallic elements like Pd and Ag could also be enriched on the PyC electrode surface using the same methodology. This paper demonstrates a remarkable advancement in the recovery of trace amounts of platinum from real industrial solutions that are not currently considered as a source of Pt metal.

KW - Circular Economy

KW - Critical Precious Metals

KW - Electrochemistry

KW - Green Chemistry

KW - Electrochemically Assisted Cementation

U2 - 10.1021/ acssuschemeng.8b03224

DO - 10.1021/ acssuschemeng.8b03224

M3 - Article

VL - 6

SP - 14631

EP - 14640

JO - ACS Sustainable Chemistry and Engineering

JF - ACS Sustainable Chemistry and Engineering

SN - 2168-0485

IS - 11

ER -

ID: 28491588