Physicochemical Modeling for Pressurized Hot Water Extraction of Spruce Wood

Research output: Contribution to journalArticleScientificpeer-review

Researchers

Research units

  • Åbo Akademi University
  • Neste Oy

Abstract

The study of reaction kinetics and process modeling plays a vital role in the development and optimization of industrial processes. In this study, a physicochemical model is presented for pressurized hot water extraction of spruce wood meal to facilitate process development and optimization. The model takes into account several relevant phenomena during the extraction process, including acid-base reaction equilibrium, irreversible reaction kinetics, ion exchange, and mass transfer. The system is modeled by assuming two liquid phases, i.e., liquid external to wood fibers and fiber-bound liquid to enable inclusion of ion exchange. The nonideal behavior of the system (due to presence of ions) is considered by utilizing activities instead of concentrations. The scission of hemicellulose polymers into oligomers and monomers is modeled by a population balance approach of discretized categories. Model parameters are optimized by fitting the model output to experimental data reported in the literature. The presented model aims to be the most comprehensive description of the phenomena taking place during the hot water extraction of softwood to date. Such physicochemical models are able to provide better understanding for parts of the process, which cannot be followed directly due to the tediousness of analytical methods. It also reveals gaps in the present knowledge and provides a step toward further development.

Details

Original languageEnglish
Pages (from-to)16664-16674
Number of pages11
JournalIndustrial and Engineering Chemistry Research
Volume57
Issue number49
Publication statusPublished - 12 Dec 2018
MoE publication typeA1 Journal article-refereed

ID: 30783505