Photoresponsive ionic liquid crystals assembled: Via halogen bond: En route towards light-controllable ion transporters

Research output: Contribution to journalArticle

Researchers

  • Marco Saccone
  • Francisco Fernandez Palacio
  • Gabriella Cavallo
  • Valentina Dichiarante
  • Matti Virkki
  • Giancarlo Terraneo
  • Arri Priimagi
  • Pierangelo Metrangolo

Research units

  • Tampere University of Technology
  • Polytechnic University of Milan

Abstract

We demonstrate that halogen bonding (XB) can offer a novel approach for the construction of photoresponsive ionic liquid crystals. In particular, we assembled two new supramolecular complexes based on 1-ethyl-3-methylimidazolium iodides and azobenzene derivatives containing an iodotetrafluoro-benzene ring as XB donor, where the iodide anion acted as an XB acceptor. DSC and X-ray diffraction analyses revealed that the preferred stoichiometry between the XB donors and acceptors is 2:1, and that the iodide anions act as bidentate XB-acceptors, binding two azobenzene derivatives. Due to the high directionality of the XB, calamitic superanions are obtained, while the segregation occurring between the charged and uncharged parts of the molecules gives rise to a layered structure in the crystal lattice. Despite the fact that the starting materials are non-mesomorphic, the halogen-bonded supramolecular complexes exhibited monotropic lamellar liquid-crystalline phases over broad temperature ranges, as confirmed with polarized optical microscopy. Due to the presence of the azobenzene moieties, the LCs were photoresponsive, and a LC-to-isotropic phase transition could be obtained by irradiation with UV light. We envisage that the light-induced phase transition, in combination with the ionic nature of the LC, provides a route towards light-induced control over ion transport and conductance in these supramolecular complexes.

Details

Original languageEnglish
Pages (from-to)407-422
Number of pages16
JournalFaraday Discussions
Volume203
Publication statusPublished - 2017
MoE publication typeA1 Journal article-refereed

ID: 17305326