Projects per year
Abstract
Heterocyclic [8]circulenes are an important class of polycyclic aromatic hydrocarbon molecules because of their unique structural properties and promising applications. However, the synthesis of heterocyclic [8]circulenes is still limited and thus is an important synthetic challenge. Here we describe the first example of a π-extended diaza[8]circulene surrounded by and fused with six hexagons and two pentagons, which was successfully synthesized only by a combined in-solution and on-surface synthetic strategy. State-of-the-art scanning tunneling microscopy with a CO-functionalized tip and density functional theory calculations revealed its planar conformation and unique electronic structure.
Original language | English |
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Pages (from-to) | 11363–11369 |
Journal | Journal of the American Chemical Society |
Volume | 142 |
Issue number | 26 |
Early online date | 1 Jan 2020 |
DOIs | |
Publication status | Published - 15 May 2020 |
MoE publication type | A1 Journal article-refereed |
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On-Surface Synthesis of a π-Extended Diaza[8]circulene
Nakamura, K. (Creator), Li, Q. (Creator), Krejci, O. (Creator), Foster, A. (Creator), Kawai, S. (Creator) & Ito, S. (Creator), 2020
Dataset
Projects
- 1 Finished
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QMKPFM: Quantum approach to modelling high resolution Kelvin Probe Force Microscopy
20/12/2019 → 04/03/2022
Project: EU: MC