Observations on the synergistic effect of adding 1-butene to systems polymerized with MgCl2/TiCl4 and Cp2ZrCl2 catalysts

Jari Koivumäki; Jukka V. Seppälä

doi:10.1021/ma00086a005

Observations on the synergistic effect of adding 1-butene to systems polymerized with MgCl2/TiCl4 and Cp2ZrCl2 catalysts

Jari Koivumäki, Jukka V. Seppälä

Research output: Contribution to journal › Article › Scientific › peer-review

27 Citations (Scopus)

Abstract

In the present work the synergistic effect was investigated on a system containing ethene, 1-butene, and long chain α-olefins (C₁₀, C₆ or C₁₈), with both Cp₂ZrCl₂ and MgCl₂/TiCl₄ catalysts. Ethene consumption was also monitored continuously and products were determined.

Original language	English
Pages (from-to)	2008-2012
Number of pages	5
Journal	Macromolecules
Volume	27
Issue number	8
DOIs	https://doi.org/10.1021/ma00086a005
Publication status	Published - 1994
MoE publication type	A1 Journal article-refereed

Keywords

1-butene
1-octadecene
ethylene
synergistic effect
terpolymerization

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10.1021/ma00086a005

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title = "Observations on the synergistic effect of adding 1-butene to systems polymerized with MgCl2/TiCl4 and Cp2ZrCl2 catalysts",

abstract = "In the present work the synergistic effect was investigated on a system containing ethene, 1-butene, and long chain α-olefins (C10, C6 or C18), with both Cp2ZrCl2 and MgCl2/TiCl4 catalysts. Ethene consumption was also monitored continuously and products were determined.",

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AU - Koivumäki, Jari

AU - Seppälä, Jukka V.

PY - 1994

Y1 - 1994

N2 - In the present work the synergistic effect was investigated on a system containing ethene, 1-butene, and long chain α-olefins (C10, C6 or C18), with both Cp2ZrCl2 and MgCl2/TiCl4 catalysts. Ethene consumption was also monitored continuously and products were determined.

AB - In the present work the synergistic effect was investigated on a system containing ethene, 1-butene, and long chain α-olefins (C10, C6 or C18), with both Cp2ZrCl2 and MgCl2/TiCl4 catalysts. Ethene consumption was also monitored continuously and products were determined.

KW - 1-butene

KW - 1-octadecene

KW - ethylene

KW - synergistic effect

KW - terpolymerization

KW - 1-butene

KW - 1-octadecene

KW - ethylene

KW - synergistic effect

KW - terpolymerization

KW - 1-butene

KW - 1-octadecene

KW - ethylene

KW - synergistic effect

KW - terpolymerization

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SP - 2008

EP - 2012

JO - Macromolecules

JF - Macromolecules

IS - 8

ER -

Observations on the synergistic effect of adding 1-butene to systems polymerized with MgCl2/TiCl4 and Cp2ZrCl2 catalysts

Abstract

Keywords

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