NOUF6 Revisited: A Comprehensive Study of a Hexafluoridouranate(V) Salt

Benjamin Scheibe; Sina Lippert; Stefan S. Rudel; Magnus R. Buchner; Olaf Burghaus; Clemens Pietzonka; Martin Koch; Antti J. Karttunen; Florian Kraus

doi:10.1002/chem.201602265

NOUF₆ Revisited: A Comprehensive Study of a Hexafluoridouranate(V) Salt

Benjamin Scheibe
, Sina Lippert
, Stefan S. Rudel
, Magnus R. Buchner
, Olaf Burghaus
, Clemens Pietzonka
, Martin Koch
, Antti J. Karttunen
, Florian Kraus^*

^*Corresponding author for this work

University of Marburg

Research output: Contribution to journal › Article › Scientific › peer-review

9 Citations (Scopus)

452 Downloads (Pure)

Abstract

We have synthesized NOUF₆ by direct reaction of NO with UF₆ in anhydrous HF (aHF). Based on the unit cell volume and powder diffraction data, the compound was previously reported to be isotypic to O₂PtF₆, however, detailed structural data, such as the atom positions and all information that can be derived from those, were unavailable. We have therefore investigated the compound by using single-crystal and powder X-ray diffraction, IR, Raman, NMR, EPR, and photoluminescence spectroscopy, magnetic measurements, as well as chemical analysis, density determination, and quantum chemical calculations.

Original language	English
Pages (from-to)	12145–12153
Journal	Chemistry: A European Journal
Volume	22
Issue number	34
DOIs	https://doi.org/10.1002/chem.201602265
Publication status	Published - 14 Jul 2016
MoE publication type	A1 Journal article-refereed

Keywords

Anhydrous hydrogen fluoride
Fluorine
Hexafluoridouranate(V)
Uranium
X-ray diffraction

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10.1002/chem.201602265

NOUF6_revisedAccepted author manuscript, 1.12 MBLicence: CC BY-NC-ND

Cite this

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title = "NOUF6 Revisited: A Comprehensive Study of a Hexafluoridouranate(V) Salt",

abstract = "We have synthesized NOUF6 by direct reaction of NO with UF6 in anhydrous HF (aHF). Based on the unit cell volume and powder diffraction data, the compound was previously reported to be isotypic to O2PtF6, however, detailed structural data, such as the atom positions and all information that can be derived from those, were unavailable. We have therefore investigated the compound by using single-crystal and powder X-ray diffraction, IR, Raman, NMR, EPR, and photoluminescence spectroscopy, magnetic measurements, as well as chemical analysis, density determination, and quantum chemical calculations.",

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author = "Benjamin Scheibe and Sina Lippert and Rudel, \{Stefan S.\} and Buchner, \{Magnus R.\} and Olaf Burghaus and Clemens Pietzonka and Martin Koch and Karttunen, \{Antti J.\} and Florian Kraus",

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month = jul,

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doi = "10.1002/chem.201602265",

language = "English",

volume = "22",

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journal = "Chemistry: A European Journal",

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TY - JOUR

T1 - NOUF6 Revisited

T2 - A Comprehensive Study of a Hexafluoridouranate(V) Salt

AU - Scheibe, Benjamin

AU - Lippert, Sina

AU - Rudel, Stefan S.

AU - Buchner, Magnus R.

AU - Burghaus, Olaf

AU - Pietzonka, Clemens

AU - Koch, Martin

AU - Karttunen, Antti J.

AU - Kraus, Florian

PY - 2016/7/14

Y1 - 2016/7/14

N2 - We have synthesized NOUF6 by direct reaction of NO with UF6 in anhydrous HF (aHF). Based on the unit cell volume and powder diffraction data, the compound was previously reported to be isotypic to O2PtF6, however, detailed structural data, such as the atom positions and all information that can be derived from those, were unavailable. We have therefore investigated the compound by using single-crystal and powder X-ray diffraction, IR, Raman, NMR, EPR, and photoluminescence spectroscopy, magnetic measurements, as well as chemical analysis, density determination, and quantum chemical calculations.

AB - We have synthesized NOUF6 by direct reaction of NO with UF6 in anhydrous HF (aHF). Based on the unit cell volume and powder diffraction data, the compound was previously reported to be isotypic to O2PtF6, however, detailed structural data, such as the atom positions and all information that can be derived from those, were unavailable. We have therefore investigated the compound by using single-crystal and powder X-ray diffraction, IR, Raman, NMR, EPR, and photoluminescence spectroscopy, magnetic measurements, as well as chemical analysis, density determination, and quantum chemical calculations.

KW - Anhydrous hydrogen fluoride

KW - Fluorine

KW - Hexafluoridouranate(V)

KW - Uranium

KW - X-ray diffraction

UR - https://www.scopus.com/pages/publications/84978436679

U2 - 10.1002/chem.201602265

DO - 10.1002/chem.201602265

M3 - Article

AN - SCOPUS:84978436679

SN - 0947-6539

VL - 22

SP - 12145

EP - 12153

JO - Chemistry: A European Journal

JF - Chemistry: A European Journal

IS - 34

ER -

NOUF₆ Revisited: A Comprehensive Study of a Hexafluoridouranate(V) Salt

Abstract

Keywords

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