TY - JOUR
T1 - NOUF6 Revisited
T2 - A Comprehensive Study of a Hexafluoridouranate(V) Salt
AU - Scheibe, Benjamin
AU - Lippert, Sina
AU - Rudel, Stefan S.
AU - Buchner, Magnus R.
AU - Burghaus, Olaf
AU - Pietzonka, Clemens
AU - Koch, Martin
AU - Karttunen, Antti J.
AU - Kraus, Florian
PY - 2016/7/14
Y1 - 2016/7/14
N2 - We have synthesized NOUF6 by direct reaction of NO with UF6 in anhydrous HF (aHF). Based on the unit cell volume and powder diffraction data, the compound was previously reported to be isotypic to O2PtF6, however, detailed structural data, such as the atom positions and all information that can be derived from those, were unavailable. We have therefore investigated the compound by using single-crystal and powder X-ray diffraction, IR, Raman, NMR, EPR, and photoluminescence spectroscopy, magnetic measurements, as well as chemical analysis, density determination, and quantum chemical calculations.
AB - We have synthesized NOUF6 by direct reaction of NO with UF6 in anhydrous HF (aHF). Based on the unit cell volume and powder diffraction data, the compound was previously reported to be isotypic to O2PtF6, however, detailed structural data, such as the atom positions and all information that can be derived from those, were unavailable. We have therefore investigated the compound by using single-crystal and powder X-ray diffraction, IR, Raman, NMR, EPR, and photoluminescence spectroscopy, magnetic measurements, as well as chemical analysis, density determination, and quantum chemical calculations.
KW - Anhydrous hydrogen fluoride
KW - Fluorine
KW - Hexafluoridouranate(V)
KW - Uranium
KW - X-ray diffraction
UR - http://www.scopus.com/inward/record.url?scp=84978436679&partnerID=8YFLogxK
U2 - 10.1002/chem.201602265
DO - 10.1002/chem.201602265
M3 - Article
AN - SCOPUS:84978436679
SN - 0947-6539
VL - 22
SP - 12145
EP - 12153
JO - CHEMISTRY: A EUROPEAN JOURNAL
JF - CHEMISTRY: A EUROPEAN JOURNAL
IS - 34
ER -