NOUF6 Revisited: A Comprehensive Study of a Hexafluoridouranate(V) Salt

Research output: Contribution to journalArticleScientificpeer-review

Researchers

  • Benjamin Scheibe
  • Sina Lippert
  • Stefan S. Rudel
  • Magnus R. Buchner
  • Olaf Burghaus
  • Clemens Pietzonka
  • Martin Koch
  • Antti Karttunen

  • Florian Kraus

Research units

  • University of Marburg

Abstract

We have synthesized NOUF6 by direct reaction of NO with UF6 in anhydrous HF (aHF). Based on the unit cell volume and powder diffraction data, the compound was previously reported to be isotypic to O2PtF6, however, detailed structural data, such as the atom positions and all information that can be derived from those, were unavailable. We have therefore investigated the compound by using single-crystal and powder X-ray diffraction, IR, Raman, NMR, EPR, and photoluminescence spectroscopy, magnetic measurements, as well as chemical analysis, density determination, and quantum chemical calculations.

Details

Original languageEnglish
Pages (from-to)12145–12153
JournalCHEMISTRY: A EUROPEAN JOURNAL
Volume22
Issue number34
Publication statusPublished - 14 Jul 2016
MoE publication typeA1 Journal article-refereed

    Research areas

  • Anhydrous hydrogen fluoride, Fluorine, Hexafluoridouranate(V), Uranium, X-ray diffraction

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