Nanostructured interpenetrated organic-inorganic aerogels with thermal superinsulating properties
Research output: Contribution to journal › Article › Scientific › peer-review
- Bayerisches Zentrum für Angewandte Energieforschung e.V.
- Mines ParisTech
Organic-inorganic composite aerogels were synthesized via a facile one-step impregnation of a wet hydrophobic cellulose II matrix with polyethoxydisiloxane solution followed by in situ NH4OH-catalysed formation of a nanostructured mesoporous silica network. The silica phase was subsequently hydrophobised with hexamethyldisilazane. By tuning synthesis conditions, organic-inorganic composite aerogels with various morphology (from meso- to macroporous), specific surface area (from 200 to 850 m2/g) and hydrophilic-hydrophobic balance (from fully hydrophilic to highly hydrophobic) were prepared after supercritical CO2 drying. The obtained organic-inorganic aerogels are monolithic, resistant to humidity and thermally superinsulating with the thermal conductivity 0.021–0.022 W/(m·K) in room conditions.
|Number of pages||7|
|Journal||Journal of Non-Crystalline Solids|
|Publication status||Published - 15 Nov 2016|
|MoE publication type||A1 Journal article-refereed|
- Aerogel, Cellulose, Composite, Interpenetrated network, Silica, Thermal conductivity