Abstract
Four N-alkyl ammonium resorcinarene halides incorporating polyiodides were obtained and structurally analyzed by single crystal X-ray crystallography. The unexpected formation of triiodides and pentaiodide anions in these structures was assumed to be the result of the heterolytic dissociation of molecular iodine (I2) in the presence of electron donors in the N-alkyl ammonium resorcinarene halide system, from which I- further binds one or two I2 molecules resulting in I3 - or I5 - species, respectively.
| Original language | English |
|---|---|
| Pages (from-to) | 5724-5727 |
| Number of pages | 4 |
| Journal | CrystEngComm |
| Volume | 18 |
| Issue number | 30 |
| DOIs | |
| Publication status | Published - Jun 2016 |
| MoE publication type | A1 Journal article-refereed |
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Datasets
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CCDC 1481998: Experimental Crystal Structure Determination
Beyeh, N. (Creator), Pan, F. (Contributor), Ras, R. (Creator) & Rissanen, K. (Contributor), Cambridge Crystallographic Data Centre , 1 Jan 2016
DOI: 10.5517/ccdc.csd.cc1lr4dw, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc1lr4dw&sid=DataCite
Dataset
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CCDC 1481999: Experimental Crystal Structure Determination
Beyeh, N. (Contributor), Pan, F. (Contributor), Ras, R. (Creator) & Rissanen, K. (Contributor), Cambridge Crystallographic Data Centre , 1 Jan 2016
DOI: 10.5517/ccdc.csd.cc1lr4fx, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc1lr4fx&sid=DataCite
Dataset
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CCDC 1481996: Experimental Crystal Structure Determination
Beyeh, N. (Creator), Pan, F. (Contributor), Ras, R. (Creator) & Rissanen, K. (Contributor), Cambridge Crystallographic Data Centre , 1 Jan 2016
DOI: 10.5517/ccdc.csd.cc1lr4bt, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc1lr4bt&sid=DataCite
Dataset