N-Alkyl ammonium resorcinarene polyiodides

Fangfang Pan; Ngong Kodiah Beyeh; Robin H A Ras; Kari Rissanen

doi:10.1039/c6ce01229a

N-Alkyl ammonium resorcinarene polyiodides

Fangfang Pan, Ngong Kodiah Beyeh^*, Robin H A Ras, Kari Rissanen

^*Corresponding author for this work

Research output: Contribution to journal › Article › Scientific › peer-review

5 Citations (Scopus)

Abstract

Four N-alkyl ammonium resorcinarene halides incorporating polyiodides were obtained and structurally analyzed by single crystal X-ray crystallography. The unexpected formation of triiodides and pentaiodide anions in these structures was assumed to be the result of the heterolytic dissociation of molecular iodine (I₂) in the presence of electron donors in the N-alkyl ammonium resorcinarene halide system, from which I^- further binds one or two I₂ molecules resulting in I₃ ^- or I₅ ^- species, respectively.

Original language	English
Pages (from-to)	5724-5727
Number of pages	4
Journal	CrystEngComm
Volume	18
Issue number	30
DOIs	https://doi.org/10.1039/c6ce01229a
Publication status	Published - Jun 2016
MoE publication type	A1 Journal article-refereed

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10.1039/c6ce01229a

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title = "N-Alkyl ammonium resorcinarene polyiodides",

abstract = "Four N-alkyl ammonium resorcinarene halides incorporating polyiodides were obtained and structurally analyzed by single crystal X-ray crystallography. The unexpected formation of triiodides and pentaiodide anions in these structures was assumed to be the result of the heterolytic dissociation of molecular iodine (I2) in the presence of electron donors in the N-alkyl ammonium resorcinarene halide system, from which I- further binds one or two I2 molecules resulting in I3 - or I5 - species, respectively.",

author = "Fangfang Pan and Beyeh, {Ngong Kodiah} and Ras, {Robin H A} and Kari Rissanen",

year = "2016",

month = jun,

doi = "10.1039/c6ce01229a",

language = "English",

volume = "18",

pages = "5724--5727",

journal = "CrystEngComm",

issn = "1466-8033",

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T1 - N-Alkyl ammonium resorcinarene polyiodides

AU - Pan, Fangfang

AU - Beyeh, Ngong Kodiah

AU - Ras, Robin H A

AU - Rissanen, Kari

PY - 2016/6

Y1 - 2016/6

N2 - Four N-alkyl ammonium resorcinarene halides incorporating polyiodides were obtained and structurally analyzed by single crystal X-ray crystallography. The unexpected formation of triiodides and pentaiodide anions in these structures was assumed to be the result of the heterolytic dissociation of molecular iodine (I2) in the presence of electron donors in the N-alkyl ammonium resorcinarene halide system, from which I- further binds one or two I2 molecules resulting in I3 - or I5 - species, respectively.

AB - Four N-alkyl ammonium resorcinarene halides incorporating polyiodides were obtained and structurally analyzed by single crystal X-ray crystallography. The unexpected formation of triiodides and pentaiodide anions in these structures was assumed to be the result of the heterolytic dissociation of molecular iodine (I2) in the presence of electron donors in the N-alkyl ammonium resorcinarene halide system, from which I- further binds one or two I2 molecules resulting in I3 - or I5 - species, respectively.

UR - http://www.scopus.com/inward/record.url?scp=84979896218&partnerID=8YFLogxK

U2 - 10.1039/c6ce01229a

DO - 10.1039/c6ce01229a

M3 - Article

AN - SCOPUS:84979896218

VL - 18

SP - 5724

EP - 5727

JO - CrystEngComm

JF - CrystEngComm

SN - 1466-8033

IS - 30

ER -

N-Alkyl ammonium resorcinarene polyiodides

Abstract

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CCDC 1481998: Experimental Crystal Structure Determination

CCDC 1481997: Experimental Crystal Structure Determination

CCDC 1481996: Experimental Crystal Structure Determination

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N-Alkyl ammonium resorcinarene polyiodides

Abstract

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Datasets

CCDC 1481998: Experimental Crystal Structure Determination

CCDC 1481997: Experimental Crystal Structure Determination

CCDC 1481996: Experimental Crystal Structure Determination

Cite this