N-Alkyl ammonium resorcinarene polyiodides

Fangfang Pan, Ngong Kodiah Beyeh*, Robin H A Ras, Kari Rissanen

*Corresponding author for this work

Research output: Contribution to journalArticleScientificpeer-review

3 Citations (Scopus)

Abstract

Four N-alkyl ammonium resorcinarene halides incorporating polyiodides were obtained and structurally analyzed by single crystal X-ray crystallography. The unexpected formation of triiodides and pentaiodide anions in these structures was assumed to be the result of the heterolytic dissociation of molecular iodine (I2) in the presence of electron donors in the N-alkyl ammonium resorcinarene halide system, from which I- further binds one or two I2 molecules resulting in I3 - or I5 - species, respectively.

Original languageEnglish
Pages (from-to)5724-5727
Number of pages4
JournalCrystEngComm
Volume18
Issue number30
DOIs
Publication statusPublished - Jun 2016
MoE publication typeA1 Journal article-refereed

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  • Cite this

    Pan, F., Beyeh, N. K., Ras, R. H. A., & Rissanen, K. (2016). N-Alkyl ammonium resorcinarene polyiodides. CrystEngComm, 18(30), 5724-5727. https://doi.org/10.1039/c6ce01229a