Projects per year
Abstract
The oxidative ring expansion of bio-derived furfuryl alcohols to densely functionalized six-membered O-heterocycles represents an attractive strategy in the growing network of valorization routes to synthetic building blocks out of the lignocellulosic biorefinery feed. In this study, two scenarios for the biocatalytic Achmatowicz-type rearrangement using methanol as terminal sacrificial reagent have been evaluated, comparing multienzymatic cascade designs with a photo-bio-coupled activation pathway.
Original language | English |
---|---|
Article number | 635883 |
Number of pages | 6 |
Journal | Frontiers in Chemistry |
Volume | 9 |
DOIs | |
Publication status | Published - 7 Apr 2021 |
MoE publication type | A1 Journal article-refereed |
Keywords
- aerobic
- enzymatic
- furans
- oxygenation
- ring expansion
- visible light
Fingerprint
Dive into the research topics of 'Methanol-Driven Oxidative Rearrangement of Biogenic Furans – Enzyme Cascades vs. Photobiocatalysis'. Together they form a unique fingerprint.Projects
- 2 Finished
-
MOCCA: Molybdenum Catalysts for C1-Carbon Valorisation
Deska, J.
01/01/2019 → 31/01/2020
Project: Academy of Finland: Other research funding
-
Beyond Biosynthesis: Enzymes as Catalysts in Non-natural Synthetic Transformations
Deska, J., Naapuri, J., Liu, Y., Blume, F., Jäger, C. & Kiefer, A.
01/09/2016 → 31/03/2021
Project: Academy of Finland: Other research funding