Metallo‐Scorpionates: First Generation of Trimetallic, Homoleptic [Ru]–M–[Ru] Complexes (M = Fe, Co, Ni, Cu)

Inge Schlapp-Hackl; Christopher Hassenrueck; Klaus Wurst; Holger Kopacka; Thomas Mueller; Reiner F. Winter; Benno Bildstein

doi:10.1002/ejic.201800774

Metallo‐Scorpionates: First Generation of Trimetallic, Homoleptic [Ru]–M–[Ru] Complexes (M = Fe, Co, Ni, Cu)

Inge Schlapp-Hackl
, Christopher Hassenrueck
, Klaus Wurst
, Holger Kopacka
, Thomas Mueller
, Reiner F. Winter
, Benno Bildstein^*

^*Corresponding author for this work

Not published at Aalto University

Research output: Contribution to journal › Article › Scientific › peer-review

Abstract

The first metallo-scorpionate ligands, closely related to Trofimenko's scorpionates, are obtained by formal replacement of the hydrido-boron moiety of hydrido-tris(pyrazolyl)borate by an (arene)RuII fragment. Coordination to divalent and trivalent 3d-transition metals (Fe, Co, Ni, Cu) gives access to a series of homoleptic, heterotrimetallic complexes containing linear metal chains bridged by pyrazole ligands. Synthetic aspects, spectroscopic, structural and electrochemical properties are reported and compared to those of standard scorpionate complexes.

Original language	English
Pages (from-to)	4434-4441
Journal	European Journal of Inorganic Chemistry
Volume	2018
Issue number	40
DOIs	https://doi.org/10.1002/ejic.201800774
Publication status	Published - Nov 2018
MoE publication type	A1 Journal article-refereed

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title = "Metallo‐Scorpionates: First Generation of Trimetallic, Homoleptic [Ru]–M–[Ru] Complexes (M = Fe, Co, Ni, Cu)",

abstract = "The first metallo-scorpionate ligands, closely related to Trofimenko's scorpionates, are obtained by formal replacement of the hydrido-boron moiety of hydrido-tris(pyrazolyl)borate by an (arene)RuII fragment. Coordination to divalent and trivalent 3d-transition metals (Fe, Co, Ni, Cu) gives access to a series of homoleptic, heterotrimetallic complexes containing linear metal chains bridged by pyrazole ligands. Synthetic aspects, spectroscopic, structural and electrochemical properties are reported and compared to those of standard scorpionate complexes.",

author = "Inge Schlapp-Hackl and Christopher Hassenrueck and Klaus Wurst and Holger Kopacka and Thomas Mueller and Winter, \{Reiner F.\} and Benno Bildstein",

year = "2018",

month = nov,

doi = "10.1002/ejic.201800774",

language = "English",

volume = "2018",

pages = "4434--4441",

journal = "European Journal of Inorganic Chemistry",

issn = "1434-1948",

publisher = "Wiley",

number = "40",

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TY - JOUR

T1 - Metallo‐Scorpionates: First Generation of Trimetallic, Homoleptic [Ru]–M–[Ru] Complexes (M = Fe, Co, Ni, Cu)

AU - Schlapp-Hackl, Inge

AU - Hassenrueck, Christopher

AU - Wurst, Klaus

AU - Kopacka, Holger

AU - Mueller, Thomas

AU - Winter, Reiner F.

AU - Bildstein, Benno

PY - 2018/11

Y1 - 2018/11

N2 - The first metallo-scorpionate ligands, closely related to Trofimenko's scorpionates, are obtained by formal replacement of the hydrido-boron moiety of hydrido-tris(pyrazolyl)borate by an (arene)RuII fragment. Coordination to divalent and trivalent 3d-transition metals (Fe, Co, Ni, Cu) gives access to a series of homoleptic, heterotrimetallic complexes containing linear metal chains bridged by pyrazole ligands. Synthetic aspects, spectroscopic, structural and electrochemical properties are reported and compared to those of standard scorpionate complexes.

AB - The first metallo-scorpionate ligands, closely related to Trofimenko's scorpionates, are obtained by formal replacement of the hydrido-boron moiety of hydrido-tris(pyrazolyl)borate by an (arene)RuII fragment. Coordination to divalent and trivalent 3d-transition metals (Fe, Co, Ni, Cu) gives access to a series of homoleptic, heterotrimetallic complexes containing linear metal chains bridged by pyrazole ligands. Synthetic aspects, spectroscopic, structural and electrochemical properties are reported and compared to those of standard scorpionate complexes.

U2 - 10.1002/ejic.201800774

DO - 10.1002/ejic.201800774

M3 - Article

SN - 1434-1948

VL - 2018

SP - 4434

EP - 4441

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 40

ER -

Metallo‐Scorpionates: First Generation of Trimetallic, Homoleptic [Ru]–M–[Ru] Complexes (M = Fe, Co, Ni, Cu)

Abstract

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