Lyotropic liquid crystals and linear supramolecular polymers of end-functionalized oligosaccharides

Teemu T. T. Myllymäki; Aynur Guliyeva; Antti Korpi; Mauri Kostiainen; Ville Hynninen; Nonappa Nonappa; Patrice Rannou; Olli Ikkala; Sami Halia

doi:10.1039/C9CC04715H

Lyotropic liquid crystals and linear supramolecular polymers of end-functionalized oligosaccharides

Teemu T. T. Myllymäki
, Aynur Guliyeva
, Antti Korpi
, Mauri Kostiainen
, Ville Hynninen
, Nonappa Nonappa
, Patrice Rannou
, Olli Ikkala
, Sami Halia

University of Grenoble

Research output: Contribution to journal › Article › Scientific › peer-review

5 Citations (Scopus)

Abstract

We synthesized permethylated maltoheptaose oligosaccharides, whose both ends, untrivially, have been functionalized with supramolecular binders 2-ureido-4[1H]-pyrimidinones (UPy) after single ring-opening of β-cyclodextrin counterpart. In 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP), they show lyotropic liquid crystallinity. In the dried state they allow linear saccharide-based supramolecular polymers by UPy-dimerization.

Original language	English
Pages (from-to)	11739-11742
Number of pages	4
Journal	Chemical Communications
Volume	55
Issue number	78
Early online date	5 Aug 2019
DOIs	https://doi.org/10.1039/C9CC04715H
Publication status	Published - 2019
MoE publication type	A1 Journal article-refereed

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10.1039/C9CC04715H

https://hal.archives-ouvertes.fr/hal-02998259/

DRIVEN: Field driven materials for functions, dissipation, and mimicking Pavlovian adaptation
Ikkala, O. (Principal investigator), Hong, X. (Project Member), Ressouche, E. (Project Member), Cherian, T. (Project Member), Kiefer, S. (Project Member), Zhang, H. (Project Member), Nath, A. (Project Member), Som, A. (Project Member), Girmay, S. (Project Member), Liang, C. (Project Member), Turunen, M. (Project Member), Eklund, A. (Project Member), Peng, B. (Project Member), Chandra, S. (Project Member), Srbova, L. (Project Member), Wani, O. (Project Member), Gustavsson, L. (Project Member), Hu, S. (Project Member), Fang, Y. (Project Member), Piho, K. (Project Member) & Lin, Z. (Project Member)
01/10/2017 → 30/09/2022
Project: EU: ERC grants

OtaNano
Rissanen, A. (Manager)
Aalto University
Facility/equipment: Facility
OtaNano - Nanomicroscopy Center
Seitsonen, J. (Manager) & Rissanen, A. (Other)
OtaNano
Facility/equipment: Facility

Cite this

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title = "Lyotropic liquid crystals and linear supramolecular polymers of end-functionalized oligosaccharides",

abstract = "We synthesized permethylated maltoheptaose oligosaccharides, whose both ends, untrivially, have been functionalized with supramolecular binders 2-ureido-4[1H]-pyrimidinones (UPy) after single ring-opening of β-cyclodextrin counterpart. In 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP), they show lyotropic liquid crystallinity. In the dried state they allow linear saccharide-based supramolecular polymers by UPy-dimerization.",

author = "Myllym{\"a}ki, \{Teemu T. T.\} and Aynur Guliyeva and Antti Korpi and Mauri Kostiainen and Ville Hynninen and Nonappa Nonappa and Patrice Rannou and Olli Ikkala and Sami Halia",

note = "| openaire: EC/H2020/742829/EU//DRIVEN",

year = "2019",

doi = "10.1039/C9CC04715H",

language = "English",

volume = "55",

pages = "11739--11742",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "78",

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TY - JOUR

T1 - Lyotropic liquid crystals and linear supramolecular polymers of end-functionalized oligosaccharides

AU - Myllymäki, Teemu T. T.

AU - Guliyeva, Aynur

AU - Korpi, Antti

AU - Kostiainen, Mauri

AU - Hynninen, Ville

AU - Nonappa, Nonappa

AU - Rannou, Patrice

AU - Ikkala, Olli

AU - Halia, Sami

N1 - | openaire: EC/H2020/742829/EU//DRIVEN

PY - 2019

Y1 - 2019

N2 - We synthesized permethylated maltoheptaose oligosaccharides, whose both ends, untrivially, have been functionalized with supramolecular binders 2-ureido-4[1H]-pyrimidinones (UPy) after single ring-opening of β-cyclodextrin counterpart. In 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP), they show lyotropic liquid crystallinity. In the dried state they allow linear saccharide-based supramolecular polymers by UPy-dimerization.

AB - We synthesized permethylated maltoheptaose oligosaccharides, whose both ends, untrivially, have been functionalized with supramolecular binders 2-ureido-4[1H]-pyrimidinones (UPy) after single ring-opening of β-cyclodextrin counterpart. In 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP), they show lyotropic liquid crystallinity. In the dried state they allow linear saccharide-based supramolecular polymers by UPy-dimerization.

U2 - 10.1039/C9CC04715H

DO - 10.1039/C9CC04715H

M3 - Article

C2 - 31513178

SN - 1359-7345

VL - 55

SP - 11739

EP - 11742

JO - Chemical Communications

JF - Chemical Communications

IS - 78

ER -

Lyotropic liquid crystals and linear supramolecular polymers of end-functionalized oligosaccharides

Abstract

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Projects

DRIVEN: Field driven materials for functions, dissipation, and mimicking Pavlovian adaptation

Equipment

OtaNano

OtaNano - Nanomicroscopy Center

Cite this