Lithium Aryloxide Thin Films with Guest-Induced Structural Transformation by ALD/MLD

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Lithium Aryloxide Thin Films with Guest-Induced Structural Transformation by ALD/MLD. / Nisula, Mikko; Linnera, Jarno; Karttunen, Antti J.; Karppinen, Maarit.

In: CHEMISTRY: A EUROPEAN JOURNAL, 2017, p. 2988 – 2992.

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@article{dbf050d1c0bd4460bea82f5c37e2d836,
title = "Lithium Aryloxide Thin Films with Guest-Induced Structural Transformation by ALD/MLD",
abstract = "Crystalline Li-organic thin films are grown with the atomic/molecular layer deposition (ALD/MLD) technique from lithium hexamethyldisilazide and hydroquinone. The as-deposited films are found to undergo a reversible structural transformation upon exposure to ambient humid air. According to density functional theory calculations, the guest-induced transformation may be related to an unsaturated Li site in the crystal structure.",
keywords = "Atomic layer deposition, Coordination polymer, Lithium organic hybrid, Molecular layer deposition, Thin film",
author = "Mikko Nisula and Jarno Linnera and Karttunen, {Antti J.} and Maarit Karppinen",
note = "| openaire: EC/FP7/339478/EU//LAYERENG-HYBMAT",
year = "2017",
doi = "10.1002/chem.201605816",
language = "English",
pages = "2988 – 2992",
journal = "CHEMISTRY: A EUROPEAN JOURNAL",
issn = "0947-6539",

}

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TY - JOUR

T1 - Lithium Aryloxide Thin Films with Guest-Induced Structural Transformation by ALD/MLD

AU - Nisula, Mikko

AU - Linnera, Jarno

AU - Karttunen, Antti J.

AU - Karppinen, Maarit

N1 - | openaire: EC/FP7/339478/EU//LAYERENG-HYBMAT

PY - 2017

Y1 - 2017

N2 - Crystalline Li-organic thin films are grown with the atomic/molecular layer deposition (ALD/MLD) technique from lithium hexamethyldisilazide and hydroquinone. The as-deposited films are found to undergo a reversible structural transformation upon exposure to ambient humid air. According to density functional theory calculations, the guest-induced transformation may be related to an unsaturated Li site in the crystal structure.

AB - Crystalline Li-organic thin films are grown with the atomic/molecular layer deposition (ALD/MLD) technique from lithium hexamethyldisilazide and hydroquinone. The as-deposited films are found to undergo a reversible structural transformation upon exposure to ambient humid air. According to density functional theory calculations, the guest-induced transformation may be related to an unsaturated Li site in the crystal structure.

KW - Atomic layer deposition

KW - Coordination polymer

KW - Lithium organic hybrid

KW - Molecular layer deposition

KW - Thin film

UR - http://www.scopus.com/inward/record.url?scp=85011411866&partnerID=8YFLogxK

U2 - 10.1002/chem.201605816

DO - 10.1002/chem.201605816

M3 - Article

SP - 2988

EP - 2992

JO - CHEMISTRY: A EUROPEAN JOURNAL

JF - CHEMISTRY: A EUROPEAN JOURNAL

SN - 0947-6539

ER -

ID: 11126203