Lithium Aryloxide Thin Films with Guest-Induced Structural Transformation by ALD/MLD

Mikko Nisula; Jarno Linnera; Antti J. Karttunen; Maarit Karppinen

doi:10.1002/chem.201605816

Lithium Aryloxide Thin Films with Guest-Induced Structural Transformation by ALD/MLD

Mikko Nisula, Jarno Linnera, Antti J. Karttunen, Maarit Karppinen^*

^*Corresponding author for this work

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Abstract

Crystalline Li-organic thin films are grown with the atomic/molecular layer deposition (ALD/MLD) technique from lithium hexamethyldisilazide and hydroquinone. The as-deposited films are found to undergo a reversible structural transformation upon exposure to ambient humid air. According to density functional theory calculations, the guest-induced transformation may be related to an unsaturated Li site in the crystal structure.

Original language	English
Pages (from-to)	2988 – 2992
Number of pages	5
Journal	CHEMISTRY: A EUROPEAN JOURNAL
DOIs	https://doi.org/10.1002/chem.201605816
Publication status	Published - 2017
MoE publication type	A1 Journal article-refereed

Keywords

Atomic layer deposition
Coordination polymer
Lithium organic hybrid
Molecular layer deposition
Thin film

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10.1002/chem.201605816

ERC-27-acceptedAccepted author manuscript, 289 KBLicence: Unspecified
ERC-27-accepted-Supporting-InfoFinal published version, 613 KBLicence: Unspecified

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title = "Lithium Aryloxide Thin Films with Guest-Induced Structural Transformation by ALD/MLD",

abstract = "Crystalline Li-organic thin films are grown with the atomic/molecular layer deposition (ALD/MLD) technique from lithium hexamethyldisilazide and hydroquinone. The as-deposited films are found to undergo a reversible structural transformation upon exposure to ambient humid air. According to density functional theory calculations, the guest-induced transformation may be related to an unsaturated Li site in the crystal structure.",

keywords = "Atomic layer deposition, Coordination polymer, Lithium organic hybrid, Molecular layer deposition, Thin film",

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AU - Nisula, Mikko

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AU - Karppinen, Maarit

N1 - | openaire: EC/FP7/339478/EU//LAYERENG-HYBMAT

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AB - Crystalline Li-organic thin films are grown with the atomic/molecular layer deposition (ALD/MLD) technique from lithium hexamethyldisilazide and hydroquinone. The as-deposited films are found to undergo a reversible structural transformation upon exposure to ambient humid air. According to density functional theory calculations, the guest-induced transformation may be related to an unsaturated Li site in the crystal structure.

KW - Atomic layer deposition

KW - Coordination polymer

KW - Lithium organic hybrid

KW - Molecular layer deposition

KW - Thin film

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Lithium Aryloxide Thin Films with Guest-Induced Structural Transformation by ALD/MLD

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Keywords

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