Intrinsic Superhydrophilicity of Titania-Terminated Surfaces

Seiji Kawasaki, Eero Holmström, Ryota Takahashi, Peter Spijker, Adam S. Foster, Hiroshi Onishi, Mikk Lippmaa

Research output: Contribution to journalArticleScientificpeer-review

8 Citations (Scopus)

Abstract

The wettability of solid surfaces is of fundamental scientific interest and related to many diverse chemical and physical phenomena at the heart of practical technologies. In particular, the hydrophilicity of the photo catalytically active metal-oxide TiO2 has attracted considerable attention for many applications. However, the intrinsic hydrophilicity of Ti-oxide surfaces is not fully understood. In this work, we investigate the intrinsic hydrophilicity of Ti-oxide surfaces on the atomically stable (root 13 x root 13)-R33.7 degrees SrTiO3 (001) surface. The surface has a TiOx double layer on a TiO2-terminated SrTiO3 (001) surface, which is available as a surface marker to assess the atomic-scale structural stability of the surface. Both experimental and theoretical results show that Ti-oxide surfaces are intrinsically superhydrophilic with a water contact angle of similar to 0 degrees. The results show that airborne surface contamination is the most significant factor affecting the wettability of titania surfaces, strongly supporting the contamination model for explaining the mechanism of photoinduced superhydrophilicity observed on titanate surfaces. We emphasize that the effect of airborne contamination has to be carefully evaluated when investigating the wettability of surfaces.

Original languageEnglish
Pages (from-to)2268-2275
Number of pages8
JournalJournal of Physical Chemistry C
Volume121
Issue number4
DOIs
Publication statusPublished - 2 Feb 2017
MoE publication typeA1 Journal article-refereed

Keywords

  • ATOMIC-FORCE MICROSCOPY
  • PHOTOINDUCED HYDROPHILICITY
  • ELECTRON-DIFFRACTION
  • MOLECULAR-DYNAMICS
  • CRYSTAL-SURFACES
  • THIN-FILM
  • TIO2
  • WATER
  • SPECTROSCOPY
  • SUBSTRATE

Cite this

Kawasaki, S., Holmström, E., Takahashi, R., Spijker, P., Foster, A. S., Onishi, H., & Lippmaa, M. (2017). Intrinsic Superhydrophilicity of Titania-Terminated Surfaces. Journal of Physical Chemistry C, 121(4), 2268-2275. https://doi.org/10.1021/acs.jpcc.6b12130