Hydrogen-assisted post-growth substitution of tellurium into molybdenum disulfide monolayers with tunable compositions

Guoli Yin, Dancheng Zhu, Danhui Lv, Arsalan Hashemi, Zhen Fei, Fang Lin, Arkady V. Krasheninnikov, Ze Zhang, Hannu Pekka Komsa*, Chuanhong Jin

*Corresponding author for this work

Research output: Contribution to journalArticleScientificpeer-review

8 Citations (Scopus)

Abstract

Herein we report the successful doping of tellurium (Te) into molybdenum disulfide (MoS2) monolayers to form MoS2xTe2(1-x) alloy with variable compositions via a hydrogen-assisted post-growth chemical vapor deposition process. It is confirmed that H2 plays an indispensable role in the Te substitution into as-grown MoS2 monolayers. Atomic-resolution transmission electron microscopy allows us to determine the lattice sites and the concentration of introduced Te atoms. At a relatively low concentration, tellurium is only substituted in the sulfur sublattice to form monolayer MoS2(1-x)Te2x alloy, while with increasing Te concentration (up to ∼27.6% achieved in this study), local regions with enriched tellurium, large structural distortions, and obvious sulfur deficiency are observed. Statistical analysis of the Te distribution indicates the random substitution. Density functional theory calculations are used to investigate the stability of the alloy structures and their electronic properties. Comparison with experimental results indicate that the samples are unstrained and the Te atoms are predominantly substituted in the top S sublattice. Importantly, such ultimately thin Janus structure of MoS2(1-x)Te2x exhibits properties that are distinct from their constituents. We believe our results will inspire further exploration of the versatile properties of asymmetric 2D TMD alloys.

Original languageEnglish
Article number145603
JournalNanotechnology
Volume29
Issue number14
DOIs
Publication statusPublished - 16 Feb 2018
MoE publication typeA1 Journal article-refereed

Keywords

  • MoS
  • post-growth
  • tellurium
  • TMDC

Fingerprint Dive into the research topics of 'Hydrogen-assisted post-growth substitution of tellurium into molybdenum disulfide monolayers with tunable compositions'. Together they form a unique fingerprint.

Cite this