Highly Chemoselective Copper-Catalyzed Conjugate Reduction of Stereochemically Labile alpha,beta-Unsaturated Amino Ketones

Andrejs Pelss, Esa T.T. Kumpulainen, Ari M.P. Koskinen

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    Abstract

    Highly chemoselective conjugate reduction of chiral R,β-unsaturated amino ketones has been developed by using triisopropyl phosphite ligated copper hydride complex. The highlights of the method are wide substrate compatibility and exceptional chemoselectivity.
    Original languageEnglish
    Pages (from-to)7598-7601
    JournalJournal of organic chemistry
    Volume74
    Issue number19
    DOIs
    Publication statusPublished - 2009
    MoE publication typeA1 Journal article-refereed

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