High-Quality Graphene Using Boudouard Reaction

Artem K. Grebenko; Dmitry V. Krasnikov; Anton V. Bubis; Vasily S. Stolyarov; Denis V. Vyalikh; Anna A. Makarova; Alexander Fedorov; Aisuluu Aitkulova; Alena A. Alekseeva; Evgeniia Gilshtein; Zakhar Bedran; Alexander N. Shmakov; Liudmila Alyabyeva; Rais N. Mozhchil; Andrey M. Ionov; Boris P. Gorshunov; Kari Laasonen; Vitaly Podzorov; Albert G. Nasibulin

doi:10.1002/advs.202200217

High-Quality Graphene Using Boudouard Reaction

Artem K. Grebenko
, Dmitry V. Krasnikov
, Anton V. Bubis
, Vasily S. Stolyarov
, Denis V. Vyalikh
, Anna A. Makarova
, Alexander Fedorov
, Aisuluu Aitkulova
, Alena A. Alekseeva
, Evgeniia Gilshtein
, Zakhar Bedran
, Alexander N. Shmakov
, Liudmila Alyabyeva
, Rais N. Mozhchil
, Andrey M. Ionov
, Boris P. Gorshunov
, Kari Laasonen
, Vitaly Podzorov
, Albert G. Nasibulin^*

^*Corresponding author for this work

Skolkovo Institute of Science and Technology
Moscow Institute of Physics and Technology
RAS - Institute of Solid State Physics
All-Russian Scientific Research Institute of Automatics
National University of Science and Technology
Donostia International Physics Center
Ikerbasque - Basque Foundation for Science
Free University of Berlin
Leibniz-Institut für Festkörper- und Werkstoffforschung
Swiss Federal Laboratories for Materials Science and Technology
RAS - Boreskov Institute of Catalysis, Siberian Branch
Moscow Engineering Physics Institute
Higher School of Economics
Rutgers, The State University of New Jersey

Research output: Contribution to journal › Article › Scientific › peer-review

43 Citations (Scopus)

280 Downloads (Pure)

Abstract

Following the game-changing high-pressure CO (HiPco) process that established the first facile route toward large-scale production of single-walled carbon nanotubes, CO synthesis of cm-sized graphene crystals of ultra-high purity grown during tens of minutes is proposed. The Boudouard reaction serves for the first time to produce individual monolayer structures on the surface of a metal catalyst, thereby providing a chemical vapor deposition technique free from molecular and atomic hydrogen as well as vacuum conditions. This approach facilitates inhibition of the graphene nucleation from the CO/CO₂ mixture and maintains a high growth rate of graphene seeds reaching large-scale monocrystals. Unique features of the Boudouard reaction coupled with CO-driven catalyst engineering ensure not only suppression of the second layer growth but also provide a simple and reliable technique for surface cleaning. Aside from being a novel carbon source, carbon monoxide ensures peculiar modification of catalyst and in general opens avenues for breakthrough graphene-catalyst composite production.

Original language	English
Article number	2200217
Number of pages	12
Journal	Advanced Science
Volume	9
Issue number	12
Early online date	20 Feb 2022
DOIs	https://doi.org/10.1002/advs.202200217
Publication status	Published - 25 Apr 2022
MoE publication type	A1 Journal article-refereed

Funding

The authors thank Mr. Andrei Starkov for illustrations and Mrs. Anastasiya Grebenko for assistance with sample synthesis. This work was performed using equipment of MIPT Shared Facilities Center. The authors acknowledge Vadim Khrapai and Evgeny Tikhonov (ISSP) for assistance with low temperature measurements and professor Galina Tsirlina (MSU) for fruitful discussions. The authors are also grateful to Salavat Khasanov for assistance and verification of XRD measurements. The authors thank the Helmholtz‐Zentrum Berlin für Materialien und Energie for the allocation of synchrotron radiation beamtime. Computations were done at the Finnish IT Center for Science, CSC. Russian Foundation for Basic Research grant # 19‐32‐90143 (A.K.G., A.G.N.). German Federal Ministry of Education and Research (BMBF) grant no. 05K19KER (A.A.M.). Russian Science Foundation No. 21‐19‐00226 (D.V.K., graphene synthesis). Russian Science Foundation No. 21‐72‐20050 (B.P.G., THz‐FIR spectroscopy). Ministry of Science and Higher Education of the Russian Federation within the governmental order for Boreskov Institute of Catalysis project АААА‐А21‐121011390011‐4 (A.N.S.). Partially supported by the Ministry of Science and Higher Education of the Russian Federation No. FSMG‐2021‐0005 (V.S.V., ARPES studies) and Russian Science Foundation No. 21‐72‐30026 (V.S.V, STM Studies). The work was supported by the Council on grants of the President of the Russian Federation grant number НШ‐1330.2022.1.3.

Keywords

Boudouard reaction
carbon monoxide
chemical vapor deposition
copper
graphene

Access to Document

10.1002/advs.202200217Licence: CC BY

CHEM_Grebenko_et_al_High‐Quality_Graphene_2022_Advanced_ScienceFinal published version, 5.51 MBLicence: CC BY

Cite this

Grebenko, A. K., Krasnikov, D. V., Bubis, A. V., Stolyarov, V. S., Vyalikh, D. V., Makarova, A. A., Fedorov, A., Aitkulova, A., Alekseeva, A. A., Gilshtein, E., Bedran, Z., Shmakov, A. N., Alyabyeva, L., Mozhchil, R. N., Ionov, A. M., Gorshunov, B. P., Laasonen, K., Podzorov, V., & Nasibulin, A. G. (2022). High-Quality Graphene Using Boudouard Reaction. Advanced Science, 9(12), Article 2200217. https://doi.org/10.1002/advs.202200217

@article{4c449850ba1c402b9de8b713ce139f5c,

title = "High-Quality Graphene Using Boudouard Reaction",

abstract = "Following the game-changing high-pressure CO (HiPco) process that established the first facile route toward large-scale production of single-walled carbon nanotubes, CO synthesis of cm-sized graphene crystals of ultra-high purity grown during tens of minutes is proposed. The Boudouard reaction serves for the first time to produce individual monolayer structures on the surface of a metal catalyst, thereby providing a chemical vapor deposition technique free from molecular and atomic hydrogen as well as vacuum conditions. This approach facilitates inhibition of the graphene nucleation from the CO/CO2 mixture and maintains a high growth rate of graphene seeds reaching large-scale monocrystals. Unique features of the Boudouard reaction coupled with CO-driven catalyst engineering ensure not only suppression of the second layer growth but also provide a simple and reliable technique for surface cleaning. Aside from being a novel carbon source, carbon monoxide ensures peculiar modification of catalyst and in general opens avenues for breakthrough graphene-catalyst composite production.",

keywords = "Boudouard reaction, carbon monoxide, chemical vapor deposition, copper, graphene",

author = "Grebenko, \{Artem K.\} and Krasnikov, \{Dmitry V.\} and Bubis, \{Anton V.\} and Stolyarov, \{Vasily S.\} and Vyalikh, \{Denis V.\} and Makarova, \{Anna A.\} and Alexander Fedorov and Aisuluu Aitkulova and Alekseeva, \{Alena A.\} and Evgeniia Gilshtein and Zakhar Bedran and Shmakov, \{Alexander N.\} and Liudmila Alyabyeva and Mozhchil, \{Rais N.\} and Ionov, \{Andrey M.\} and Gorshunov, \{Boris P.\} and Kari Laasonen and Vitaly Podzorov and Nasibulin, \{Albert G.\}",

note = "Funding Information: The authors thank Mr. Andrei Starkov for illustrations and Mrs. Anastasiya Grebenko for assistance with sample synthesis. This work was performed using equipment of MIPT Shared Facilities Center. The authors acknowledge Vadim Khrapai and Evgeny Tikhonov (ISSP) for assistance with low temperature measurements and professor Galina Tsirlina (MSU) for fruitful discussions. The authors are also grateful to Salavat Khasanov for assistance and verification of XRD measurements. The authors thank the Helmholtz‐Zentrum Berlin f{\"u}r Materialien und Energie for the allocation of synchrotron radiation beamtime. Computations were done at the Finnish IT Center for Science, CSC. Russian Foundation for Basic Research grant \# 19‐32‐90143 (A.K.G., A.G.N.). German Federal Ministry of Education and Research (BMBF) grant no. 05K19KER (A.A.M.). Russian Science Foundation No. 21‐19‐00226 (D.V.K., graphene synthesis). Russian Science Foundation No. 21‐72‐20050 (B.P.G., THz‐FIR spectroscopy). Ministry of Science and Higher Education of the Russian Federation within the governmental order for Boreskov Institute of Catalysis project АААА‐А21‐121011390011‐4 (A.N.S.). Partially supported by the Ministry of Science and Higher Education of the Russian Federation No. FSMG‐2021‐0005 (V.S.V., ARPES studies) and Russian Science Foundation No. 21‐72‐30026 (V.S.V, STM Studies). The work was supported by the Council on grants of the President of the Russian Federation grant number НШ‐1330.2022.1.3. Publisher Copyright: {\textcopyright} 2022 The Authors. Advanced Science published by Wiley-VCH GmbH",

year = "2022",

month = apr,

day = "25",

doi = "10.1002/advs.202200217",

language = "English",

volume = "9",

journal = "Advanced Science",

issn = "2198-3844",

publisher = "Wiley",

number = "12",

}

Grebenko, AK, Krasnikov, DV, Bubis, AV, Stolyarov, VS, Vyalikh, DV, Makarova, AA, Fedorov, A, Aitkulova, A, Alekseeva, AA, Gilshtein, E, Bedran, Z, Shmakov, AN, Alyabyeva, L, Mozhchil, RN, Ionov, AM, Gorshunov, BP, Laasonen, K, Podzorov, V & Nasibulin, AG 2022, 'High-Quality Graphene Using Boudouard Reaction', Advanced Science, vol. 9, no. 12, 2200217. https://doi.org/10.1002/advs.202200217

TY - JOUR

T1 - High-Quality Graphene Using Boudouard Reaction

AU - Grebenko, Artem K.

AU - Krasnikov, Dmitry V.

AU - Bubis, Anton V.

AU - Stolyarov, Vasily S.

AU - Vyalikh, Denis V.

AU - Makarova, Anna A.

AU - Fedorov, Alexander

AU - Aitkulova, Aisuluu

AU - Alekseeva, Alena A.

AU - Gilshtein, Evgeniia

AU - Bedran, Zakhar

AU - Shmakov, Alexander N.

AU - Alyabyeva, Liudmila

AU - Mozhchil, Rais N.

AU - Ionov, Andrey M.

AU - Gorshunov, Boris P.

AU - Laasonen, Kari

AU - Podzorov, Vitaly

AU - Nasibulin, Albert G.

N1 - Funding Information: The authors thank Mr. Andrei Starkov for illustrations and Mrs. Anastasiya Grebenko for assistance with sample synthesis. This work was performed using equipment of MIPT Shared Facilities Center. The authors acknowledge Vadim Khrapai and Evgeny Tikhonov (ISSP) for assistance with low temperature measurements and professor Galina Tsirlina (MSU) for fruitful discussions. The authors are also grateful to Salavat Khasanov for assistance and verification of XRD measurements. The authors thank the Helmholtz‐Zentrum Berlin für Materialien und Energie for the allocation of synchrotron radiation beamtime. Computations were done at the Finnish IT Center for Science, CSC. Russian Foundation for Basic Research grant # 19‐32‐90143 (A.K.G., A.G.N.). German Federal Ministry of Education and Research (BMBF) grant no. 05K19KER (A.A.M.). Russian Science Foundation No. 21‐19‐00226 (D.V.K., graphene synthesis). Russian Science Foundation No. 21‐72‐20050 (B.P.G., THz‐FIR spectroscopy). Ministry of Science and Higher Education of the Russian Federation within the governmental order for Boreskov Institute of Catalysis project АААА‐А21‐121011390011‐4 (A.N.S.). Partially supported by the Ministry of Science and Higher Education of the Russian Federation No. FSMG‐2021‐0005 (V.S.V., ARPES studies) and Russian Science Foundation No. 21‐72‐30026 (V.S.V, STM Studies). The work was supported by the Council on grants of the President of the Russian Federation grant number НШ‐1330.2022.1.3. Publisher Copyright: © 2022 The Authors. Advanced Science published by Wiley-VCH GmbH

PY - 2022/4/25

Y1 - 2022/4/25

N2 - Following the game-changing high-pressure CO (HiPco) process that established the first facile route toward large-scale production of single-walled carbon nanotubes, CO synthesis of cm-sized graphene crystals of ultra-high purity grown during tens of minutes is proposed. The Boudouard reaction serves for the first time to produce individual monolayer structures on the surface of a metal catalyst, thereby providing a chemical vapor deposition technique free from molecular and atomic hydrogen as well as vacuum conditions. This approach facilitates inhibition of the graphene nucleation from the CO/CO2 mixture and maintains a high growth rate of graphene seeds reaching large-scale monocrystals. Unique features of the Boudouard reaction coupled with CO-driven catalyst engineering ensure not only suppression of the second layer growth but also provide a simple and reliable technique for surface cleaning. Aside from being a novel carbon source, carbon monoxide ensures peculiar modification of catalyst and in general opens avenues for breakthrough graphene-catalyst composite production.

AB - Following the game-changing high-pressure CO (HiPco) process that established the first facile route toward large-scale production of single-walled carbon nanotubes, CO synthesis of cm-sized graphene crystals of ultra-high purity grown during tens of minutes is proposed. The Boudouard reaction serves for the first time to produce individual monolayer structures on the surface of a metal catalyst, thereby providing a chemical vapor deposition technique free from molecular and atomic hydrogen as well as vacuum conditions. This approach facilitates inhibition of the graphene nucleation from the CO/CO2 mixture and maintains a high growth rate of graphene seeds reaching large-scale monocrystals. Unique features of the Boudouard reaction coupled with CO-driven catalyst engineering ensure not only suppression of the second layer growth but also provide a simple and reliable technique for surface cleaning. Aside from being a novel carbon source, carbon monoxide ensures peculiar modification of catalyst and in general opens avenues for breakthrough graphene-catalyst composite production.

KW - Boudouard reaction

KW - carbon monoxide

KW - chemical vapor deposition

KW - copper

KW - graphene

UR - https://www.scopus.com/pages/publications/85124839935

U2 - 10.1002/advs.202200217

DO - 10.1002/advs.202200217

M3 - Article

AN - SCOPUS:85124839935

SN - 2198-3844

VL - 9

JO - Advanced Science

JF - Advanced Science

IS - 12

M1 - 2200217

ER -

High-Quality Graphene Using Boudouard Reaction

Abstract

Funding

Keywords

Access to Document

Other files and links

Fingerprint

Producing High-Quality Graphene Cheaply Using Carbon Monoxide

Cite this

High-Quality Graphene Using Boudouard Reaction

Abstract

Funding

Keywords

Access to Document

Other files and links

Fingerprint

Press/Media

Producing High-Quality Graphene Cheaply Using Carbon Monoxide

Cite this