Giant Negative Terahertz Photoconductivity in Controllably Doped Carbon Nanotube Networks

Research output: Contribution to journalArticleScientificpeer-review

Researchers

  • Maria G. Burdanova
  • Alexey P. Tsapenko
  • Daria A. Satco
  • Reza Kashtiban
  • Connor D.W. Mosley
  • Maurizio Monti
  • Michael Staniforth
  • Jeremy Sloan
  • Yuriy G. Gladush
  • Albert Nasibulin

  • James Lloyd-Hughes

Research units

  • University of Warwick
  • Skolkovo Institute of Science and Technology

Abstract

A strong negative photoconductivity was identified in thin film networks of single-walled carbon nanotubes using optical pump, THz probe spectroscopy. The films were controllably doped, using either adsorption doping with different p-type dopant concentrations or ambipolar doping using an ionic gate. While doping enhanced the THz conductivity and increased the momentum scattering rate, interband photoexcitation lowered the spectral weight and reduced the momentum scattering rate. This negative THz photoconductivity was observed for all doping levels, regardless of the chemical potential, and decayed within a few picoseconds. The strong many-body interactions inherent to these 1D conductors led to trion formation under photoexcitation, lowering the overall conductivity of the carbon nanotube network. The large amplitude of negative THz photoconductivity and the tunability of its recovery time with doping offer promise for spectrally wide-band ultrafast devices, including THz detectors, polarizers, and modulators.

Details

Original languageEnglish
Pages (from-to)1058-1066
Number of pages9
JournalACS Photonics
Volume6
Issue number4
Publication statusPublished - 17 Apr 2019
MoE publication typeA1 Journal article-refereed

    Research areas

  • carbon nanotubes, negative photoconductivity, terahertz spectroscopy

ID: 33653786