Furfural production in a biphasic system using a carbonaceous solid acid catalyst

Gerardo Gomez Millan, Josphat Phiri, Mikko Mäkelä, Thaddeus Maloney, Alina Balu, Antonio Pineda, Jordi Llorca, Herbert Sixta

Research output: Contribution to journalArticleScientificpeer-review

9 Citations (Scopus)
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Abstract

The formation of furfural from xylose was investigated under heterogeneously catalyzed conditions with sulfated Starbon as a catalyst in a biphasic system. The experiments were perfomed based on the basis of a statistical experimental design. The variables considered were time, temperature and the ratio of aqueous to organic phase. The results indicate that sulfated Starbon is an effective solid acid catalyst for furfural formation. Starbon was characterised by scanning electron microscopy, N2-physisorption, thermogravimetric analysis, diffuse reflectance infrared Fourier transform, Raman spectroscopy and titration with pyridine. The maximum furfural yield and selectivity of 70 mol% were achieved with complete xylose conversion under the optimum experimental conditions. The present paper suggests that functionalized Starbon can be employed as an efficient solid acid catalyst that has significant hydrothermal stability and can be reused for several cycles to produce furfural from xylose.
Original languageEnglish
JournalAPPLIED CATALYSIS A-GENERAL
DOIs
Publication statusPublished - 2019
MoE publication typeA1 Journal article-refereed

Keywords

  • Furfural
  • Xylose
  • Starbon
  • Biphasic system
  • CPME
  • Biomass

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