Experimental thermodynamic study on the Ag-Sb system at elevated temperatures

Research output: Chapter in Book/Report/Conference proceedingConference contributionScientificpeer-review

Abstract

In this paper, the standard thermodynamic properties of Ag3Sb and Ag6Sb intermetallic compounds have been studied by the solid state EMF-method, using Ag+ ion conducting β- Alumina and Ag+. The intermetallic compounds were synthesized from pure substances in evacuated silica ampoules and their formation were confirmed by the SEM-EDS analyses. The EMF measurements were made on electrochemical cells of the type [Ag | β-alumina | Ag-Sb] and [Ag | Agl | Ag-Sb], The usage of β-alumina electrolyte, in this study, enabled thermodynamic measurements of the Ag-Sb-intermetallic compounds above 710 K, hitherto unreported. Based on the new experimental data, thermodynamic properties of the Ag-Sb-intermetallic compounds have been determined. The obtained experimental values have been compared with the available literature data.

Original languageEnglish
Title of host publicationEPD Congress 2015 - Held During TMS 2015 144th Annual Meeting and Exhibition
PublisherMINERALS, METALS AND MATERIALS SOCIETY
Pages305-312
Number of pages8
Volume2015-January
EditionJanuary
ISBN (Electronic)9781119093503
ISBN (Print)9781119082453
DOIs
Publication statusPublished - 2015
MoE publication typeA4 Article in a conference publication
EventTMS Annual Meeting and Exhibition - Orlando, United States
Duration: 15 Mar 201519 Mar 2015
Conference number: 144

Conference

ConferenceTMS Annual Meeting and Exhibition
Abbreviated titleTMS
CountryUnited States
CityOrlando
Period15/03/201519/03/2015

Keywords

  • Electrochemistry
  • Emf technique
  • Gibbs energy of formation

Fingerprint Dive into the research topics of 'Experimental thermodynamic study on the Ag-Sb system at elevated temperatures'. Together they form a unique fingerprint.

Cite this