Excess properties from pρT data for n-heptane + isomeric chlorobutane mixtures

Hernando Guerrero, Félix M. Royo, Ignacio Gascón, Carlos Lafuente*

*Corresponding author for this work

Research output: Contribution to journalArticleScientificpeer-review

1 Citation (Scopus)

Abstract

The densities of the binary mixtures n-heptane + isomeric chlorobutane have been determined in a wide range of both temperatures and pressures (T = 283.15-323.15 K, p = 0.1-65.0 MPa). From experimental densities different excess volumetric properties have been estimated. The results have been discussed taking into account both molecular interactions and structural effects operating in the mixing process. In addition, the densities of the mixtures have been satisfactorily predicted using the VTPR model.

Original languageEnglish
Pages (from-to)100-109
Number of pages10
JournalThermochimica Acta
Volume614
DOIs
Publication statusPublished - 29 Jun 2015
MoE publication typeA1 Journal article-refereed

Keywords

  • Density
  • Excess property
  • Heptane
  • Isomeric chlorobutanes
  • VTPR model

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